基本情况
姓名：陈小明
性别：男
籍贯：暂未填写
职位：教授，博士生导师，曾任生物无机与合成化学教育部重点实验室主任
联系方式
邮箱：cxm@mail.sysu.edu.cn
通讯地址：广州市新港西路中山大学化学与化学工程学院
邮编：510275
教育经历
1983年获中山大学理学学士学位；
1986年获中山大学理学硕士学位；
1992年获香港中文大学哲学博士学位。
工作经历
主要工作简历：
1986年至1989年在中山医科大学生物化学教研室工作，历任助教、讲师
1992年7月起在中山大学化学与化学工程学院工作
1993年12月晋升副教授，1995年1月晋升教授
2006年至今，生物无机与合成化学教育部重点实验室主任
主要学术兼职：
先后兼任生物无机与合成化学教育部重点实验室主任、中大化学院院长、中国晶体学会副理事长、中国科学院化学部常委及副主任、国家学位委员会化学学科评议组成员、国家基金委化学部专家咨询委员会成员、国际分子筛协会金属有机框架材料（MOF）委员会成员等职务等。
讲授课程
主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程；指导博士后、博士生、硕士生以及国内访问学者的科研工作。
科研方向
功能配位化学与晶体工程研究，特别是配位聚合物、金属有机框架材料等的设计与合成、结构与功能（吸附与分离、催化、光电磁、传感）研究，以及含能分子晶体研究。
获奖情况
2007年 国家自然科学奖二等奖（第一完成人）：配合物控制合成与晶体工程方法基础研究
2008年 汤森路透卓越研究奖 (Thomson Reuters Research Fronts Award)
2012年 发展中国家科学院TWAS化学奖
2012年 广东省科学技术奖一等奖(第一完成人): “微孔与磁性配位聚合物研究”
2014年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2015年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2016年 汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2017年 科睿唯安高被引用科学家 (Clarivate Highly Cited Researcher)
2017年 广东省科学技术奖突出贡献奖
论著一览
编写教材：
《单晶结构分析原理与实践》（与蔡继文博士合作），科学出版社，2003年9月第一版，2007年8月第二版。
陈小明在国际刊物发表的部分论文目录：
Selected Publications of Xiao-Ming Chen:
1. Polynuclear CuII12-MIII6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion:
[Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601. PDF
2. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N. Angew. Chem. Int. Ed. 1999, 38, 2237-2240. PDF
3. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031. PDF
4. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883. PDF
5. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202. PDF
6. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209.
7. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219. PDF
8. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565. PDF
9. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506. PDF
10. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082. PDF
11. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163. PDF
12. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559. PDF
13. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314. PDF
14. (Review Article) Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170. PDF
15. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498. PDF
16. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China) PDF
17. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739. PDF
18. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538. PDF
19. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017; PDF
20. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2009, 131, 5516–5521. (Highlighted in Nature China) Link.
21. (Review Article) Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M., Chem. Soc. Rev. 2009, 38, 2385–2396. Link
22. A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2009, 48, 5287-5290. Link.
23. Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2010, 132, 6654–6656. Link
24. Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M., Adv. Mater. 2011, 22, 1268–1271. PDF
25. A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2011, 2, 2214-2218. Link.
26. Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2012, 3, 642.DOI: 10.1038/ncomms1654. Link
27. (Review Article) Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M., Chem. Rev. 2012, 112, 1001–1033. Link
28. Strong and dynamic CO2 sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc.2012, 134, 17380-17383. Link
29. A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 351–356. Link
30. Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 1539-1546. Link
31. Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2013, 4, 2534. DOI: 10.1038 /ncomms3534. Link
32. A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.; Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2013, 52, 13429-13433. Link
33. (Invited Review) Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M., Chem. Soc. Rev. 2014, 43, 5789-5814. DOI: 10.1039/C4CS00129J. Link
34. Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M., Adv. Funct. Mater. 2014, 24, 5866–5872. DOI: 10.1002/adfm.201401125. Link
35. Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen, Chem. Sci. 2014, 5, 4755. DOI: 10.1039/C4SC01505C. Link
36. Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming;Angew. Chem. Int. Ed. 2015, 54, 914 –918. DOI: 10.1002/anie.201408491. Link
37. Monodentate hydroxide as a super strong yet reversible active site for CO2 capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting; Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen, Energy Environ. Sci. 2015, 8, 1011-1016. DOI: 10.1039/C4EE02717E. Link
38. Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.; Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6350. doi:10.1038/ncomms7350. Link
39. Tuning fluorocarbon adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2015, 6, 2516-2521. DOI: 10.1039/C4SC03985H. Link
40. Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6917. DOI: doi: 10.1038/ncomms7917. Link
41. (Invited Review) Metal cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen, Coord. Chem. Rev. 2015, 293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009. Link
42. Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna, Rajamani; Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2015, 137, 7217–7223. Link
43. Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8348. DOI: 10.1038/ncomms9348. Link
44. Efficient purification of ethene by ethane-trapping metal-organic framework
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8697. doi:10.1038/ncomms9697. Link
45. (Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 4674–4678. DOI: 10.1002/anie.201511006. Link
46. An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei; Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming, J. Am. Chem. Soc. 2016, 138, 8336–8339. DOI: 10.1021/jacs.6b03125.Link
47. Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming; Adv. Mater., 2016, 28, 5886–5890. DOI: 10.1002/adma.201600895. Link
48. (Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO2
Kai-Jie Chen, David G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko, Angew. Chem. Int. Ed. 2016,55, 10268–10272. DOI: 10.1002/anie.201603934. Link
49. Putting ultrahigh concentration of amine groups into a metal–organic framework for CO2 capture at low pressures
Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong; Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci. 2016, 7, 6528-6533. DOI: 10.1039/C6SC00836D. Link
50. Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 6021–16025. DOI: 10.1002/anie.201608439. Link
51. Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 1778–1781. DOI: 10.1021/jacs.6b12353. Link
52. A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan; He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 139, 5285–5288. DOI: 10.1021/jacs.7b00165. Link
53. A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 6369–6375. DOI: 10.1021/jacs.7b01334. Link
54. Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Science, 2017, 356, 1193-1196. DOI: 10.1126/science.aam7232. Link
55. A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi; Zhang, Wei-Xiong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 8086–8089. DOI: 10.1021/jacs.7b02981. Link
56. Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2017, 8, 7560–7565. DOI: 10.1039/c7sc03067c. Link
57. Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO2 reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng; J. Am. Chem. Soc.2018, 140, 38–41. Link
58. Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long; Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming, Zhang, Jie-Peng; Adv. Mater. 2018, 30, 1704350. adma.201704350. Link
59. Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu, Xia; Du, Zi-Yi; He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming,Angew. Chem. Int. Ed. 2018, 10.1002/anie.201802580. Link