基本情况

姓名:张伟雄

性别:男

出生年月:1981-11

籍贯:广东梅州

职位:教授,博士生导师

 

联系方式

电话:+86-20-84110517

传真:暂未填写

邮箱:zhangwx6@mail.sysu.edu.cn

通讯地址:广州市新港西路135号中山大学丰盛堂

邮编:510275

个人网站:暂未填写

 

教育经历

2004.09—2009.06:中山大学,无机化学专业硕博连读,博士
2000.09—2004.06:中山大学,应用化学专业,学士

 

工作经历

2018.04至今:中山大学化学学院,教授
2012.08—2018.04:中山大学化学学院,副教授
2010.06—2012.08:日本东北大学,日本学术振兴会(JSPS)博士后
2009.07—2010.06:中山大学化学学院,科研助理

 

讲授课程

基础化学实验I(无机,2012-2014)
基础化学实验IV(综合,2013-2014)
无机化学(地理科学本科生,2013)
现代无机化学进展(化学,2014-)
综合化学实验(化学,2014-)
高等无机化学(研究生,2016-)
单晶结构分析(研究生,2012-)

 

科研方向

功能配合物的晶体工程,特别是结构相变功能配合物和含能分子晶体的设计组装与性能研究。已发表论文100余篇,他引5000多次,13篇入选ESI高引论文;H指数为38。 Researcher ID: D-3365-2011 (http://www.researcherid.com/rid/D-3365-2011)

 

科研项目

国家自然科学基金优青项目,21722107,2018-2020
国家自然科学基金面上项目,21671202,2017-2020
国家自然科学基金青年项目,21301198,2014-2016
科技部“国家重大科学仪器设备开发专项”子任务,2013YQ24051102,2013.10-2017.9
广东省特支计划科技创新青年拔尖人才项目,2015TQ01C250,2016-2019
广州市“珠江科技新星”项目,201610010027,2016.5-2019.4
广东省自然科学基金自由申请项目,S2013010012186,2013.10-2015.10
教育部博士点新教师类基金,20130171120002,2014.01-2016.12
中山大学青年教师重点培育项目,16lgzd10,2016-2017
中山大学百人计划启动基金,2012-2014

 

获奖情况

2017 国家优秀青年科学基金
2016 广东省特支计划科技创新青年拔尖人才
2016 广州市珠江科技新星
2015 化学与化学工程学院“87奖教金”
2014 广东省千百十人才培养工程校级培养对象
2012 中山大学“百人计划”引进人才

 

论著一览

综述与专著章节:

4) Zhang W.-X.; Zeng M.-H.; Chen X.-M. Porous Molecular Magnets, Molecular Magnetic Materials: Concepts and Applications Editor: Barbara Sieklucka, Dawid Pinkowicz, Wiley-VCH Verlag GmbH & Co. KGaA, 2017: 253-278 (Book Chapter)

3) Xu W.-J.; Du Z.-Y.; Zhang W.-X.*; Chen X.-M. Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges CrystEngComm 2016, 18, 7915-7928.

2) Zhang W.-X.*; Liao P.-Q.; Lin R.-B.; Wei Y.-S.; Zeng M.-H.*; Chen X.-M.* Metal cluster-based functional porous coordination polymers Coord. Chem. Rev. 2015, 293-294, 263-278.

1) Zhang W.-X.*; Ishikawa R.; Breedlove B. K.; Yamashita H.* Single-chain magnets: beyond the Glauber model RSC Adv. 2013, 3, 3772−3798.

 

部分论文目录(* 表示通讯联系人)

 

 

 

2018

49) Chen S.-L.; Yang Z.-R.; Wang B.-J.; Shang Y.; Sun L.-Y.; He C.-T.; Zhou H.-L.; Zhang W.-X.*; Chen X.-M.* Molecular perovskite high-energetic materials Sci. Chin. Mater. 2018, DOI: 10.1007/s40843-017-9219-9.

48) Xu W.-J.; Zeng Y.; Yuan W.; Qiu R.-G.; Zhang W.-X.*; Chen X.-M. Room-temperature optic-electric duple bistabilities induced by plastic transition Chem. Commun. 2018, 54, 3347-3350.

47) Wang S.-S.; Chen X.-X.; Huang B.; Su Y.-J.; Zhang W.-X.*; Zeng M.-H.; Chen X.-M. Bromocholine bromide is a molecular ferroelectric with moderate phase transition temperature J. Mater. Chem. C 2018, 6, 2221-2224.

46) Mo Z.-W.; Zhou H.-L.; Zhou D.-D.; Lin R.-B.; Liao P.-Q.; He T.-C.; Zhang W.-X.; Chen X.-M.; Zhang J.-P.* Mesoporous metal–organic frameworks with exceptionally high working capacities for adsorption heat transformation Adv. Mater. 2018, 30, 1704350.

 

 

2017

45) Xu W.-J.; Li P.-F.; Tang Y.-Y.; Zhang W.-X.*; Xiong R.-G.; Chen X.-M. A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics J. Am. Chem. Soc. 2017, 139, 6369-6375. (Highlighted in Science)

44) Li W.; He C.-T.; Zeng Y.; Ji C.-M.; Du Z.-Y.*; Zhang W.-X.*; Chen X.-M. A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds J. Am. Chem. Soc. 2017, 139, 8086-8089.

43) Huang B.; Sun L.-Y.; Wang S.-S.; Zhang J.-Y.; Ji C.-M.; Luo J.-H.; Zhang W.-X.*; Chen X.-M. A near-room-temperature organic–inorganic hybrid ferroelectric: [C6H5CH2CH2NH3]2[CdI4Chem. Commun. 2017, 53, 5764.

42) Zeng Y.; Huang R.-K..; Du Z.-Y.*; He C.-T.; Zhang W.-X.*; Chen X.-M. Matching of Host−Guest Symmetry/Orientation and Molecular Dynamics in Two Double Perovskite-Like Azido Coordination Polymers Inorg. Chem. 2017, 56, 9946-9953.

41) Su Y.-J.; Wei K.-X.; Huang B.; Xu W.-J.; Zhang W.-X.*; Zeng M.-H.; Chen X.-M. Deformable Mn(III)–Schiff-base dimer for anomalously large positive and negative anisotropic thermal expansions CrystEngComm 2017, 19, 1725-1728.

40) Du Z.-Y.; Zhang L.; Wang B.-Y.; Liu S.-J.*; Huang B.; Liu C.-M.*; Zhang W.-X.* Two magnetic Δ-chain-based Mn(II) and Co(II) coordination polymers with mixed carboxylate–phosphinate and μ3-OH bridges CrystEngComm 2017, 19, 1052-1057.

39) Su Y.-J.; Xu K.; Yuan W.; Huang Y.-K.; Zhang W.-X.; Chen X.-M.* Phase transitions of two coordination polymers [MCl2(β-ala)]n (M = Co, Ni; β-ala = 3-Aminopropionic Acid) Chin.J. Inorg. Chem. 2017, 33, 2005-2010.

38) Liao P.-Q.; Huang N.-Y.; Zhang W.-X.; Zhang J.-P.*; Chen X.-M. Controlling guest conformation for efficient purification of butadieneScience 2017, 356, 1193-1196.

37) Sheng J.-Q.; Liao P.-Q.; Zhou D.-D.; He C.-T.; Wu J.-X.; Zhang W.-X.; Zhang J.-P.*; Chen X.-M. Modular and stepwise synthesis of a hybrid metal−organic framework for efficient electrocatalytic oxygen evolution J. Am. Chem. Soc. 2017, 139, 1778-1781.

 

 

2016

36) Shi Q.; Xu W.-J.; Huang R.-K.; Zhang W.-X.*; Li Y.; Wang P.-F.; Shi F.-N.*; Li L.-B.; Li J.-P.; Dong J.-X.* Zeolite CAN and AFI-type ZIFs with large 12-MR pore openings synthesized using bulky amides as structure-directing agents J. Am. Chem. Soc.2016, 138, 16232-16235.

35) Xu, W.-J.; He, C.-T.; Ji, C.-M.; Chen, S.-L.; Huang, Y.-K.; Lin, R.-B.; Luo, J.-H.; Zhang, W.-X.*; Chen, X.-M. Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches, Adv. Mater. 2016,28, 5886.

34) Huang B.; Wang B.-Y.; Du Z.-Y. Xue W.; Xu W.-J.; Su Y.-J.; Zhang W.-X.*; Zeng M.-H.; Chen X.-M. Importing spontaneous polarization into a Heisenberg ferromagnet for a potential single-phase multiferroic J. Mater. Chem. C 2016, 4, 8704.

33) Sun Y.-Z.; Huang B.; Xu W.-J.; Zhou D.-D.; Chen S.-L.; Zhang S.-Y.; Du Z.-Y.* Xie Y.-R.; He  C.-T.*; Zhang W.-X.*; Chen X.-M. Plastic crystals with polar halochromate anion: thermosensitive dielectrics based upon plastic transition and dipole rotation Inorg. Chem. 2016, 55, 11418.

32) Xu W.-J.; Xie K.-P.; Xiao Z.-F.; Zhang W.-X.*; Chen X.-M. Controlling two-step phase transitions and dielectric responses by A‑site cations in two perovskite-like coordination polymers Cryst. Growth Des. 2016, 16, 7212-7217.

31) Xu W.-J.; Chen S.-L.; Hu Z.-T.; Lin R.-B.; Su Y.-J.; Zhang W.-X.*; Chen X.-M.* The cation-dependent structural phase transition and dielectric response in a family of cyanobridged perovskite-like coordination polymers Dalton Trans. 2016, 42, 4224-4229.

30) Xie K.-P.; Xu W.-J.; He C.-T.; Huang B.; Du Z.-Y.; Su Y.-J.; Zhang W.-X.*; Chen X.-M. Order–disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH4]2[NiCd(SCN)6CrystEngComm 2016, 18, 4495.

 

2015

29) Du Z.-Y.; Xu T.-T.; Huang B.;Su Y.-J.; Xue W.; He C.-T.; Zhang W.-X.*; Chen, X.-M. Switchable guest molecular dynamics in a Perovskite-like coordination polymer toward sensitive thermo-responsive dielectric materials Angew. Chem. Int. Ed. 2015, 54, 914.

28) Du Z.-Y.*; Sun Y.-Z.; Chen S.-L.; Huang B.; Su Y.-J.; Xu T.-T.; Zhang W.-X.*; Chen X.-M. Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks Chem. Commun. 2015, 51, 15641.

27) Bai J.; Zhou H.-L.; Liao P.-Q.; Zhang W.-X.*; Chen X.-M. Structural diversity of coordination polymers controlled by the metal ion as the sole reaction variable CrystEngComm 2015, 17, 4462-4468.

26) Wang B. Y; He C. T.; Huang B.; Xu W. J.; Xue W.; Du Z. Y.; Zhang W.-X.*; Chen X.-M. Thermal-induced reversible ferroelastic phase transition in a new bromethyl-substituted molecular rotor Sci. Chin. Chem. 2015, 58, 1137.

25) Liao P.-Q.; Zhang W.-X.; Zhang J.-P.*; Chen X.-M. Efficient purification of ethene by an ethane-trapping metal-organic framework Nat. Commun. 2015, 6, 8697.

24) Liao P.-Q.; Zhu A.-X.; Zhang W.-X.; Zhang J.-P.*; Chen X.-M. Self-catalysed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors Nat. Commun. 2015, 6, 6350. 

 

2014

23) He C.-T.; Liao P.-Q.; Zhou D.-D.; Wang B.-Y.; Zhang W.-X.*; Zhang J.-P.*; Chen X.-M. Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behavior of interpenetration-direction isomeric coordination networks Chem. Sci. 2014, 5, 4755-4762.

22) Du Z.-Y.; Zhao Y.-P.; Zhang W.-X.*; Zhou H.-L.; He C.-T.; Xue W.; Wang B.-Y.; Chen, X.-M. Above-room-temperature ferroelastic phase transition in a perovskite-like cage compound [N(CH3)4][Cd(N3)3Chem. Commun. 2014, 50, 1989–1991.

21) Du Z.-Y.; Zhao Y.-P.; He C.-T.; Wang B.-Y.; Xue W.; Zhou H.-L.; Bai J.; Huang B,; Zhang W.-X.*; Chen X.-M.* Structural transition in the perovskite-like bimetallic azido coordination polymers: (NMe4)2[B'*B''(N3)6] (B' = Cr3+, Fe3+; B'' = Na+, K+Cryst. Growth Des. 2014, 14, 3903–3909.

20) Wang B.-Y.; Xu W.-J.; Xue W.; Lin R.-B.; Du Z.-Y.; Zhou D.-D.; Zhang W.-X.*; Chen X.-M. Restraining the motion of ligand for modulating the structural phase transition in two isomorphic polar coordination polymers Dalton Trans. 2014, 43, 9008-9011.

19) Li F.; Lin Y.-B.; Wei Y.-S.; Liao P.-Q.; Bai J.; Xue W.; Zhang W.-X.*; Zhang J.-P.*; Chen X.-M. Metal-ion controlled solid-state reactivity and photoluminescence in two isomorphous coordination polymers Inorg. Chem. Front. 2014, 1, 172–177.

18) Zeng M.-H.*; Yin Z.; Tan Y.-X.; Zhang W.-X.; He Y.-P.; Kurmoo M. Nanoporous cobalt(II) MOF exhibiting four magnetic ground states and changes in gas sorption upon post-synthetic modification J. Am. Chem. Soc. 2014, 136, 4680–4688.

 

2013

17) Qi X.-L.; Zhang C.; Wang B.-Y.; Xue W.; He C.-T.; Liu S.-Y.; Zhang W.-X.*; Chen X.-M.* Two new polar coordination polymers with diamond networks: interpenetration and thermal phase transition  CrystEngComm 2013, 15, 9530−9536.

 

2012

16) Zhang W.-X.*; Shiga T.; Miyasaka H.; Yamashita H.* New approach for designing single-chain magnets: organization of chains via hydrogen bonding between nucleobases J. Am. Chem. Soc. 2012, 134, 6908−6911.

 

2011年以前

15) Zhang W.-X.; Xue W.; Chen X.-M.* Flexible mixed-spin Kagome coordination polymers with reversible magnetism triggered by dehydration and rehydration Inorg. Chem. 2011, 50, 309−316.

14) Zhang W.-X.; Xue W.; Zheng Y.-Z.; Chen X.-M.* Two spin-competing manganese(II) coordination polymers exhibiting unusual multi-step magnetization jumps Chem. Commun. 2009, 3804−3806.

13) Zhang W.-X.; Xue W.; Lin J.-B.; Zheng Y. Z.; Chen X.-M.* 3D geometrically frustrated magnets assembled by transition metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes CrystEngComm 2008, 10, 1770−1776.

12) Zhang W.-X.; Yang Y.-Y.*; Zai S.-B.; Ng S.-W.; Chen X.-M.* Syntheses, structures and magnetic properties of dinuclear Copper(II)-Lanthanide(III) complexes bridged by 2-hydroxymethyl-1-methylimidazole Eur. J. Inorg. Chem. 2008, 679−685.

11) Zhang Y.-B.; Zhang W.-X.; Feng F.-Y., Zhang J.-P.*; Chen X.-M.* A highly-connected porous coordination polymer with interesting channel structure and sorption properties Angew. Chem., Int. Ed. 2009, 48, 5287–5290.

10) Cheng X. N.; Zhang W.-X.; Chen X.-M.* Single crystal-to-single crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer J. Am. Chem. Soc. 2007, 129, 15738−15739.

9) Cheng X.-N.; Zhang W.-X.; Lin Y.-Y.; Zheng Y.-Z.; Chen X.-M.* A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Adv. Mater. 2007, 19, 1494−1498.

8) Wang W.-G.; Zhou A.-J.; Zhang W.-X.; Tong M.-L.*; Chen X.-M.; Nakano, M.; Beedle, C. C.; Hendrickson, D. N.* Giant heterometallic Cu17Mn28 cluster with Td symmetry and high-spin ground state J. Am. Chem. Soc. 2007, 129, 1014−1015.

7) Zhang X.-M.*; Hao, Z.-M.; Zhang W.-X.; Chen X.-M. Dehydration-induced conversion from a single-chain magnet into a metamagnet in a homometallic nanoporous metal-organic framework Angew. Chem., Int. Ed. 2007, 46, 3456−3459.

6) Zheng Y.-Z.; Tong M.-L.; Xue W.; Zhang W.-X.; Chen X.-M.*; Grandjean, F.; Long, G. J.* A "Star" antiferromagnet: A polymeric iron(III) acetate that exhibits both spin frustration and long-range magnetic ordering Angew. Chem., Int. Ed. 2007, 46, 6076−6080.

5) Zhang X.-M.*; Zhao Y.-T.; Zhang W.-X.; Chen X.-M. A tetrazolate- and cyano-bridged homometallic mixed-valence copper(I,II) molecular ferrimagnet Adv. Mater. 2007, 19, 2843−2846. 

4) Zeng M.-H.*; Yao M.-X.; Liang H.*; Zhang W.-X.; Chen X.-M. A single-molecule-magnetic, cubane-based, triangular Co12supercluster Angew. Chem., Int. Ed. 2007, 46, 1832−1835.

3) Zheng Y.-Z.; Tong M.-L.; Zhang W.-X.; Chen X.-M.* Assembling magnetic nanowires into networks: A layered Co(II) carboxylate coordination polymer exhibiting single-chain-magnet behavior Angew. Chem., Int. Ed. 2006, 45, 6310−6314.

2) Zhang J.-P.; Lin Y.-Y.; Zhang W.-X.; Chen X.-M.* Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer J. Am. Chem. Soc. 2005, 127, 14162−14163.

1) Zeng M.-H.; Zhang W.-X.; Sun X.-Z.; Chen X.-M.* Spin canting and metamagnetism in a 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II)-coordination-polymer sheets Angew. Chem., Int. Ed. 2005, 44, 3079−3082.

 

相关成果

 

1. 张伟雄、陈劭力、陈小明,一类化合物在作为含能材料方面的用途,中国发明专利,ZL 201610665880.3

2. 张伟雄、许伟剑、陈劭力、陈小明,一种新型高温铁电体及其制备方法,中国发明专利,201710281982.X

3. 张伟雄、黄波、郑赛利、薛玮、陈小明,一种多铁性化合物及其制备方法,中国发明专利,ZL 201510291844.0