Prof. Dr. h.c. Hansjörg Grützmacher

主要研究兴趣：光引发剂；氢化和脱氢反应的分子催化剂；磷化合物可持续合成方法（招收硕士生，博士生，博士后）

e-mail: hgruetzmacher@ethz.ch   lizhsh6@mail.sysu.edu.cn

 

  ACADEMIC CAREER

June 2025 – Present:          Full professor of organic Chemistry at the SYSU

Oct. 2001 – July 2024:      Full professor of Inorganic Chemistry at the ETH Zürich

Oct. 1995 –Sept. 2001:    Extraordinary professor of Inorganic Chemistry at the ETH Zürich

Oct. 1992-Sept. 1995:     Professorof Inorganic and Analytical Chemistry at the University of Freiburg

March-Sept. 1992:           Privatdozent at the University of Heidelberg

Nov. 1987-Jan. 1992:      Habilitand at the Inorganic Institute of the University Heidelberg

Nov. 1986-Oct. 1987:      Chargé de recherche at the CNRS Toulouse, Laboratoire de Chimie de Coordination (Dir. Dr. G. Bertrand)

 

 Visiting Professorships

Since 2012:                           Visiting professor at the LIFM, IGCME, School of Chemistry, Sun Yat-Sen University,       510006 Guangzhou, China

2010:                                    Visiting professor at the ICCOM-CNR, Florence, Italy

 

2001 - 2006 :                        Professeur chargé de cours at the Ecole Polytechnique, Paris-Palaiseau

 

2004 - 2005 :                        Visiting professor at the Université des Antilles et de la Guyane

  EDUCATION

 

Jan. 1992:             Habilitation at the University of Heidelberg

                            Title of Thesis: "Phosphor- and Tin Compounds with Weak p-Bonds: Synthesis, Structures and Reactivity".

 

Oct. 1986:            PhD at the University of Göttingen under the supervision of Prof. Dr. H.W. Roesky. Title of Thesis: "Trifluoromethyl Substituted Heterocycles".

 

May 1984:            Diploma at the University of Göttingen under the supervision of Prof. Dr. H.W. Roesky. Title of       Thesis: "Reactions of Disulfides, Epoxides and Episulfides in Presence of Silver(I)-Ions".

 

Oct. 1978:             Inscription into the courses of chemistry at the University of Göttingen.

 

  Awards

  1. Liebig-scolar of the Fonds of the Chemical Industry 1987 - 1989

  2. Scholarship of the German National Science Foundation 1989 - 1991

  3. Annual Award for Habilitands of the German Chemical Society 1991

  4. Award of the Dr. Otto-Röhm-Memorial Foundation 1991

  5. Karl-Winnacker-Scholarship 1992

  6. Heisenberg-Scholarship of the German Chemical Society 1992

  7. Karl-Freudenberg Award of the Academy of Sciences of Heidelberg 1992

  8. Carl-Duisberg-Memorial Award of the German Chemical Society 1993

  9. Participant of the Scientia Europea 1998

  10. Bryan E. Kohler Lecturer at the University of Riverside, California 2006

  11. Sandmeyer Award of the Swiss Chemical Society 2007

  12. Xerox lecturer at the University of British Columbia 2009

  13. Egon Wiberg lecturer at the Ludwig-Maximilian-University, Munich 2011

  14. R.J.P. Williams Lecturer at the University of Oxford, Oxford, 2012

  15. Hofmann Distinguished Lecture, Imperial College London, 2013

  16. Curator of the Journal Angewandte Chemie, 2014 - 2018.

  17. Wilhelm Klemm Award of the German Chemical Society, 2017.

  18. Honorary doctoral degree of Budapest University of Technology and Economics, 2021.

  19. Charles P. Casey lecture at the University of Wisconsin, Madison, USA,2022

  20. Demarçay lecture Ecole Polytechnique Paris Palaiseau 2022.

  21. Nomination to Distinguished Professor of Chemistry at the Lehn Institute of 

Functional Materials at the Sun-Yat-Sen University, China, 2023.

 

Industrial Co-operations

 

  1. Immobilisation of Oxidation Catalysts (Ciba Speciality Chemicals)
  2. BABAR-Phos Complexes (BASF)
  3. Development of New Photoinitiators (Ciba Speciality Chemicals, then BASF, then IGM speciality chemicals)
  4. Ligands for Catalysis (LANXESS)
  5. Selective Dehydrogenation of Sulfur Containing Compounds (DEGUSSA)
  6. Renewable Fuel Cells (ICCOM), I
  7. Process for the modification of polymer nanoparticles, Max-Planck-Institut, D
  8. Synthesis of phosphanes from PH3 (PhoSmart)
  9. Application of Photoinitiators (Altana)

Memberships

  1. Chairman of the Institute of Inorganic Chemistry 2004 – 2006

  2. Member of the Steering Committee ICPC 2010.

  3. Member of the Management Committee (MC, Swiss Representative) of the COST Action CM0802.

  4. Member of the ERC Advanced Grant evaluation panel.

  5. President of the planning commission for studies in chemistry at ETH-Zürich 1996 - 2001.

  6. Member of the planning commission "Studies in Chemistry Switzerland" 1996 - 2000

  7. Member of the Advisory Board of the Journal "Dalton Transactions”

  8. Member of the Advisory Board of the Journal "European Journal of Inorganic Chemistry" 

  9. Member of the Editorial Board of the Journal "Main Group Chemistry"

  10. Mobility Advisor, Department of Chemistry and Applied Biosciences –since 2010

  11. Chairman of the Institute of Inorganic Chemistry 2010 – 2012

  12. Member of the selection committee of the Heilbronner-Hückel-Vorlesung

  13. Curator of the Angewandte Chemie, 2014 - 2018.

 

Publications（Since 2020）

  1. N-Heterocyclic Carbene Stabilized Dicarbondiphosphides: Strong Neutral Four-Membered Heterocyclic 6 -Electron Donors, Z. Li, X. Chen, L. Liu, M. Scharnhölz, H. Grützmacher, Angew. Chem. Int. Ed., 2020, 59, 4288-4293.

  2. Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent, A. Cosola, R. Conti, V. K. Rana, M. Sangermano, A. Chiappone, J. Levalois-Grützmacher, H. Grützmacher, Chem. Comm., 2020, 56, 4825-4831.

  3. An In-Depth Mechanistic Study of Ru-Catalysed Aqueous Methanol Dehydrogenation and Prospects for Future Catalyst Design, N. Govindarajan, V. Sinha, M. Trincado, H. Grützmacher, E. J. Meijer, B. de Bruin, ChemCatChem, 2020, 12, 2610-2621.

  4. Development and characterisation of a nanostructured hybrid material with vitamin B12 and bagasse-derived activated carbon for anaerobic chlordecone (Kepone) removal, R. Ranguin, M. C. Ncibi, T. Cesaire, S. Lavoie, C Jean-Marius, H. Grützmacher, S. Gaspard, Environ Sci Pollut Res, 2020, 27, 41122-41131.

  5. Hydrogenolysis of Polysilanes Catalyzed by Low-Valent Nickel Complexes, B. Pribanic, M. Trincado, F. Eiler, M. Vogt, A. Comas-Vives, H. Grützmacher, Angew.Chem. 2020, 59, 15603-15609.

  6. 1,3,4-Azadiphospholides as Building Blocks for Scorpionate and bidentate Ligands in Multinuclear Complexes, R. Suter, M. Wagner, L. Querci, Z. Benkö, H. Grützmacher, Dalton Trans., 2020, 49, 8201-8208.

  7. The Underlying Chemistry to the Formation of PO2 Radicals from Organophosphorus Compounds: a Missing Puzzle Piece in Flame Chemistry, S. Liang, P. Hemberger, M. Steglich, P. Simonetti, J. Levalois-Grützmacher, H. Grützmacher, S. Gaan, Chem. Eur. J., 2020, 26, 10795-10800.

  8. A Single Molecular Stoichiometric P-Source for Phase-Selective Synthesis of Crystalline and Amorphous Iron Phosphide Nanocatalysts, F. D’Accriscio, E. Schrader, C. Sassoye, M. Selmane, R. F. André, S. Lamaison, D. Wakerley, M. Fontecave, V. Mougel, G. Le Corre, H. Grützmacher, C. Sanchez, S. Carenco, ChemNanoMat, 2020, 6, 1208-1219.

  9. White CsPbBr3: Characterizing the One-Dimensional Cesium Lead Bromide Polymorph, M. Aebli, B. M. Benin, K. M. McCall, V. Morad, D. Thöny, H. Grützmacher, M. Kovalenko, Helv. Chim. Acta, 2020, 103, e2000080.

  10. In vitro Implementation of Photopolymerizable Hydrogels as a Potential Treatment of Intracranial Aneurysms, O. Poupart, A. Schmocker, R. Conti, C. Moser, K. M. Nuss, H. Grützmacher, P. J. Mosimann, D. P. Pioletti, Frontiers in Bioengineering and Biotechnology, 2020, 8, 261.

  11. Deoxygenative Fluorination of Phosphine Oxides: A General Route to Fluorinated Organophosphorus(V) Compounds and Beyond, D. Bornemann, C. Ross Pitts, L. Wettstein, F. Brüning, S. Küng, L. Guan, N. Trapp, H. Grützmacher, A. Togni, Angew. Chem. Int. Ed., 2020, 59, 22790-22795.

  12. Multiacrylated Cyclodextrin: A Bio-Derived Photocurable Macromer for VAT 3D Printing, A. Cosola, R. Conti, H. Grützmacher, M. Sangermano, I. Roppolo, C. F. Pirri, A. Chiappone, Macromol. Mater. Eng., 2020, 305, 2000350-2000356.

  13. Isomerism and Biradical Character of Tetrapnictide Dianions: A computational Study, P. Coburger, R. Wolf, H. Grützmacher, Eur. J. Inorg. Chem., 2020, 3580-3586.

  14. A Room-Temperature Stable Distonic Radical Cation, X. Chen, L. L. Liu, S. Liu, H. Grützmacher, Z. Li, Angew. Chem. Int. Ed., 2020, 59, 23830-23835.

  15. Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with Π-Conjugated Central Seven- and Eight-Membered Rings, J. Bloch, S. Kradolfer, T. L. Gianetti, D. Ostendorf, S. Dey, V. Mougel, H. Grützmacher, Molecules, 2020, 25, 4742-4765.

  16. Desoxyfluorierung von Phosphanoxiden: Ein allgemeiner Weg zu fluorierten Organophosphor(V)-Verbindungen und noch mehr, Angew. Chem., 2020, 132, 22982-22988.

  17. Phosphinine-based ligands: Recent developments in coordination chemistry and applications, N. T. Coles, A. S. Abels, J. Leitl, R. Wolf, H. Grützmacher, C. Müller, Coordination Chemistry Reviews, 2021, 432, 213729.

  18. Anionic 1-Aza-3,4-Diphospholides as redox active ligands, R. Suter, R. J. Gilliard, J. Iskandarov, Z. Benkö, M. Wörle, H. Grützmacher, Inorg. Chim. Acta, 2021, 120274.

  19. Pulsatile Flow-Induced Fatigue-Resistant Photopolymerizable Hydrogels for the Treatment of Intracranial Aneurysms, O. Poupart, R. Conti, A. Schmocker, L. Pancaldi, C. Moser, K. M. Nuss, M. S. Sakar, T. Dobrocky, H. Grützmacher, P. J. Mosimann, D. P. Pioletti, Front. Bioeng. Biotechnol., 2021, 8, 619858.

  20. Coordination-induced polymerization of P=C bonds leads to regular (P-C)n polycarbophosphanes, Y. Mei, J. J. Gamboa Carballo, Y. Bao, N. Wu, G. Le Corre, H. Grützmacher, Sci. Adv., 2021, online.

  21. DLP 3D – printing of shape memory polymers stabilized by thermoreversible hydrogen bonding interactions, A. Cosola, M. Sangermano. D. Terenziani, R. Conti M. Messori, H. Grützmacher C. F. Pirri, A. Chiappone, Appl. Mat. Tod.2021, 23, 101060.

  22. Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report, M. Trincado, J. Bösken, H. Grützmacher, Coord. Chem. Rev.,2021, 213967.

  23. Vibrational Spectrum and Photochemistry of Phosphaketene HPCO, W. Oian, B. Lu, G. Rauhut, H. Grützmacher, X. Zeng, Phys. Chem. Chem. Phys., 2021, 23, 19237-19243.

  24. Reduction of Nitrogen Oxides by Hydrogen with Rhodium(I)-Platinum(II) Olefin Complexes as Catalysts, P. Jurt, A. Abels, J. J. Gamboa Carballo, I. Fernández, G. Le Corre, M. Aebli, M. G. Baker, F. Eiler, F. Müller, M. Wörle, R. Verel, S. Gauthier, M. Trincado, T. L. Gianetti, H. Grützmacher, Angew. Chem. Int. Ed., 2021, 60, 25372-25380.

  25. From polysaccharides to UV-curable biorenewable organo/hydrogels for methylene blue removal, C. Noè, A. Cosola, A. Chiappone, M. Hakkarainen, H. Grützmacher, M. Sangermano, Polymer, 2021, 235, 124257.

  26. Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules, G. Le Corre, J. J. Gamboa-Carballo, Z. Li, Hansjörg Grützmacher, Angew. Chem. Int. Ed.,2021, 60, 24817-24822.

  27. Solvent-Free Three-Dimensional Printing of Biodegradable Elastomers Using Liquid Macrophotoinitiators, M. Sandmeier, N. Paunovic, R. Conti, L. Hofmann, J. Wang, Z. Luo, K. Masania, N. Wu, N. Kleger, F. B. Coulter, A. R. Studart, H. Grützmacher, J.-C. Leroux, Y. Bao, Macromolecules, 2021, 54, 7830-7839.

  28. Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation, F. J. de Zwart, V. Sinha, M. Trincado, H. Grützmacher, B. de Bruin, Dalton Trans., 2022, 51, 3019-3026.

  29. Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide, G. Le Corre, H. Grützmacher, Dalton Trans., 2022, 51, 3497.

  30. Remarkable stability of a molecular ruthenium complex in PEM water electrolysis, M. Bellini, J. Bösken, M. Wörle, D. Thöny, J.J. Gamboa-Carballo, F. Krumeich, F. Bàrtoli, H. A. Miller, L. Poggini, W. Oberhauser, A. Lavacchi, H. Grützmacher, F. Vizza, Chem. Sci., 2022, 13, 3748-3760.

  31. Trigonal Bipyramidal Rhodium(I) Methyl and Phenyl Complexes: Precursors of Oxidative Methyl and Phenyl Radical Generation, U. Fischbacher, M. Vogt, P. Coburger, M. Trincado, H. Grützmacher, Inorganics, 2022,10, 28.

  32. White phosphorus first, H. Grützmacher, Nature Chem., 2022, 14, 361-364.

  33. Insertion of Ruthenium into an inorganic, cyclic biradicaloid, J. Oswald, M. T. Scharnhölz, P. Coburger, H. Beer, J. Bresien, A. Schulz, H. Grützmacher, Z. Anorg. Allg. Chem., 2022, e202200093.

  34. Bis(imidazolium)-1,3-diphosphete-diide: A Building Block for FeC2P2 Complexes and Clusters, M. T. Scharnhölz, P. Coburger, L. Gravogl, D. Klose, J. J. Gamboa-Carballo, G. Le Corre, J. Bösken, C. Schweinzer, D. Thöny, K. Meyer, Z. Li, H. Grützmacher, Angew. Chem. Int. Ed. Engl. 2022, e202205371.

  35. Heavier bis(m-terphenyl)etement phosphaethynolates of group 13, D. Duvinage, M. Janssen, E. Lork, H. Grützmacher, S. Mebs, J. Beckmann, Dalton Transactions, 2022, 51, 7622-762. 

  36. Recyclable Mn(I) Catalysts for Base-Free Asymmetric Hydrogenation: Mechanistic, DFT and Catalytic Studies, H. Jayaprakash, P. Coburger, M. Wörle, A. Togni, H. Grützmacher, Chemistry - A European Journal, 2022, 28, e202201522.

  37. Kinetic Stabilization of Heavier Bis(m-terphenyl)pnictogen Phosphaethynolates, D. Duvinage, M. Janssen, E. Lork, H. Grützmacher, S. Mebs, J. Beckmann, Zeitschrift für anorganische und allgemeine Chemie, 2022, 648, e202200133.

  38. A Germapyramidane Switches Between 3D Cluster and 2D Cyclic Structures in Single-Electron Steps, P. Coburger, F. Masero, J. Bösken, V. Mougel, H. Grützmacher, Angewandte Chemie. Int. Ed., 2022, 61, e202211749.

  39. Bis(acyl)phosphine Oxides as Stoichiometric Photo-Reductants for Copper Nanoparticle Synthesis: Efficiency and Kinetics, M. Schmallegger, H. Grützmacher, G. Gescheidt, ChemPhotoChem2022, e202200155.

  40. Organocatalyzed Phospha-Michael Addition: A Highly Efficient Synthesis of Customized Bis(acyl)phosphane Oxide Photoinitiators, R. Conti, A. Widera, G. Müller, C. Fekete, D. Thöny, F. Eiler, Z. Benkö, H. Grützmacher, Chem. Eur. J., 2023, 29, e202202563.

  41. A comparative study of biradicaloids as ligands in iron tetracarbonyl complexes, M. T. Scharnhölz, P. Coburger, H. Beer, J. Bresien, A. Schulz, H. Grützmacher, Arkivoc 2022, part iii, 327 – 338.
  42. The coordination chemistry of 2,4,6-oxy functionalised 1,3,5-triphosphinines, Dalton Transactions, 2023, DOI: 10.1039/D3DT00057E 
  43. ACTIVE-BAPO – A Versatile Transfer Agent for Photoactive Bis(acyl)phosphane Oxide Units, A. Widera, R. Conti, A. Cosola, A. Fäh, D. Thöny, M. Sangermano, J. Levalois-Grützmacher, H. Grützmacher, Chem. Eur. J.2023, 29, e202203842.

  44. Reduction of Nitrous Oxide by Light Alcohols Catalysed by a Low-Valent Ruthenium Diazadiene Complex, J. Bösken, R. E. Rodríguez-Lugo, S. Nappen, M.Trincado, H. Grützmacher, Chem. Eur. J. 2023, e202203632.

  45. Reversible Single Electron Redox Steps Convert Polycycles with a C3P3 Core to a Planar Triphosphinine, P. Coburger, C. Schweinzer, Z. Li, H. Grützmacher, Angew. Chem. Int. Ed.2023, 62, e202214548.

  46. Tough PEG-only hydrogels with complex 3D structure enabled by digital light processing of “all-PEG” resins, S. Noor Anindita, R. Conti, D. Zauchner, N. Paunović, W. Qiu, M. Green Buzhor, A. Krivitsky, Z. Luo, R. Müller, H. Grützmacher, X.-H. Qin, J.-C. Leroux, Y. Bao, Aggregate2023; DOI: 10.1002/agt2.368. 

  47. The Chemistry of the Cyaphide Ion, T. Görlich, P. Coburger, E. Yang, J. Goicoechea, H. Grützmacher, C. Müller, Angew. Chem. Int. Ed. 2023, 62, e202217749.

  48. Bis(acyl)phosphide - Ambidentate Ligands for the Synthesis of Group 14 and 15 Main Group Element Compounds, A. Widera, R. Conti, E. Schrader, M. Aebli, M. Wörle, H. Grützmacher, ChemPlusChem2023, 88, e202200451.

  49. Solid-State Investigation, Storage, and Separation of Pyrophoric PH3 and P2H4 with -Mg Formate, A. Widera, D. Thöny, M. Aebli, J. Jacob Oppenheim, J. Andrews, F. Eiler, M. Wörle, H. Schönberg, N. Weferling, M. Dincǎ, H. Grützmacher, Angew. Chem. Int. Ed. 2023, 62, e202217534.

  50. Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry, J. Lin, S. Liu, J. Zhang, H. Grützmacher, C.-Y. Su, Z. Li, Chem. Sci., 2023, 14, 10944.

  51. Symmetrical and Mixed Tris(acyl)phosphines: Synthesis, Oxidation and Photochemistry, T. Wiesner, D. Neshchadin, G. Glotz, Z. Gfader, E. Schrader, S. Christen, R. C. Fischer, A.-M. Kelterer, G. Gescheidt, H. Grützmacher, M Haas, Chem. Eur. J.2023, 29, e202303527

  52. Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes, D. Himmelbauer, F. Müller, C. Schweinzer, F. Casas, B. Pribanic, G. Le Corre, D. Thöny, M. Trincado, H. Grützmacher, Chem. Commun., 2024, 60, 885 – 888.

  53. A Simple Manganese(I) Catalyst for the Efficient and Selective Hydrophosphination of Olefins with PH3, Primary, and Secondary Phosphanes, A.A. Wani, J. J. Gamboa-Carballo, H. Jayaprakash, M. Wörle, A. Widera, A. Togni, H. Grützmacher, Chem. Eur. J.2024, e202303848.

  54. Cobalt catalyzed practical hydroboration of terminal alkynes with time-dependent stereoselectivity J. Wen, Y. Huang, Y. Zhang, H. Grützmacher, P. Hu, Nat. Commun.2024, 25, 2208.

  55. Structural Changes in the Carbon Sphere of a Dirhodium Complex Induced by Redox or Deprotonation Reactions, C. Schweinzer, P. Coburger, H. Grützmacher, Adv. Sci.2024, 2400072.

  56. (Ph3P)4C4P4: Effect of substitution on the Oligomerization of carbon phosphide radicals, M. Scharnhölz, J. J. Gamboa Carballo, N. Trapp, R. Verel, P. Coburger, H. Grützmacher, Chem. Eur.2024, e202400061.

  57. Tailored Bisacylphosphane Oxides for Precise Induction of Oxidative Stress-Mediated Cell Death in Biological Systems, K. Almahayani, J.B. Salvador, R. Conti, A. Widera, M. Spiekremann, D. Wehner, H. Grützmacher, L. Möckl, ACS Chem. Bio.2025, 20, 77-85. 

  58. Beyond absorption maxima: the impact of wavelength-resolved photochemistry on materials science, Q. Thijssen, J. A. Carroll, F. Feist, A. Beil, H. Grützmacher, M. Wegener, S. Van Vlierberghe, C. Barner-Kowollik, Mater. Horiz.,2024, 11, 6184-6191

  59. Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes, P. Jurt, J. J. Gamboa-Carballo, C. Schweinzer, D. Himmelbauer, D.Thöny, T. L. Gianetti, M. Trincado, H. Grützmacher, Dalton Trans.,2024, 53, 14212 – 14218.

  60. Sequential radical and cationic reactivity at separated sites within one molecule in solution, S. Liu, Y. Li, J. Lin, Z. Ke, C.-Y. Su, Z. Li, H. Grützmacher Chem. Sci.,2024, 15, 5376 – 5384.

  61. Diphosphaenones: beyond the phosphorus analogue of enones, J. Lin, S. Liu, S. Zheng, H. Grützmacher, Z. Li, Chem. Sci.2024, 15, 20030-20038.

  62. A Genuine Trivalent Bis-Acylphosphide (BAP) Complex of Uranium, J. Hochholzer, P. Waldschmidt, F. W. Heinemann, H. Grützmacher, K. Meyer, Eur. J. Inorg. Chem.,2024, 27 e202300592.

  63. Heterogeneous Fe-N-C Cocatalyst for Hydroquinone Oxidation Enables Aerobic Oxidation of Primary Alcohols to Aldehydes, A. Hoque, C. Schweinzer, J.J. Martinez, F. Tewes, V. Sacchetti, H. Grützmacher, S. S. Stahl, Angew. Chem. Int. Ed.2025, e202424778.

  64. Cl3Al®PH3 is a Weak Lewis Pair Allowing the Synthesis of Sterically Highly Hindered Primary and Secondary Alkyl Phosphanes, H. Grützmacher, J. Oswald, C. Fekete, M. Baker, M. Bispinghoff, P.G. Pringle, N. Weferling, Z. Benkő, Angew. Chem. Int. Ed.2025, e202501656.
  65. Water Serving as Cocatalyst for the Highly Efficient Homogeneously Catalyzed Conversion of N2O/H2 Mixtures with Optimized Rhodium NHC Complexes, S. T. Nappen, J. J. Gamboa-Carballo, E. Tschannen, F. Ricatto, M. D. Wörle, A. Thomas, M. Trincado, H. Grützmacher, Angew. Chem. Int. Ed.2025, e202502616.

 

Books & book chapters

  1. Catalytic Heterofunctionalisation, A. Togni, H. Grützmacher (Eds.), Wiley-VCH, Weinheim 2001.

  2. New Perspectives for Olefin Complexes: Synthesis and Characterization of Stable Rhodium(0) and Iridium(0) Complexes, J. Harmer1, G. Frison2, M. Rudolph3, H. Schönberg2, S. Deblon2, P. Maire2, S. Boulmâaz, F. Breher2, C. Böhler2 , H. Rüegger2, A. Schweiger1 and H. Grützmacher, in Perspectives in Organometallic Chemistry (C.G. Screttas, B. Steele, Eds.), Royal Chemical Society, Cambridge 2003, 222-239.

  3. The Organometallic Chemistry of Rh, Ir, Pd and Pt based Radicals Part I: Higher Valent Species, D. G. H. Hetterscheid, A. Koekkoek, H. Grützmacher, B. de Bruin, Prog .Inorg. Chem.2007, 55, 249-354.

  4. Synthesis and Recycling of Six Different Nickel Complexes, H Schönberg, H. Grützmacher in Experiments in Green and Sustainable Chemistry (H. W. Roesky, D. K. Kennepohl, Eds.), Wiley-VCH 2009, 184-193.

  5. Cooperating Ligands in Catalysis, M. Trincado, H. Grützmacher in Cooperative Catalysis (Ed. René Peters), Wiley-VCH 2014, 67-111.

  6. CO2-based hydrogen storage – Hydrogen generation from formaldehyde/water, M. Trincado, H. Grützmacher, M. Prechtl in Physical Sciences Reviews, De Gruyter, 2018, online. 

Patents

  1. Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale, H. Grützmacher, R. Sommerlade, S. Boulmaâz, EP 1 103 537 A1; Process for the selective oxidation of alcohols using readily removable nitroxyl radicals, U.S. 27.08.2002, No. 6,441,243.

  2. Liganden zur Anwendung in katalytischen Prozessen, H. Grützmacher, S. Deblon, P. Maire, H. Schönberg, 2002, DE 101 59 015.6; EP0213533.

  3. Process for converting alcohols to carbonyl compounds, S. Boulmaâz, H. Schönberg, H. Grützmacher, 05.04.2002, EP02/405269.8; WO 03/084911 A1.

  4. Verfahren zur Herstellung von Additionsprodukten ethylenisch ungesättigter Verbindungen, J. Liedtke, H. Grützmacher, 2002, DE 101 17 677.

  5. Verfahren zur Synthese von Cycloorganylphosphanen und von Di(alkali/erdalkalimetall)oligo­phosphandiiden, H. Grützmacher, J. Geier, H. Schönberg, M. Scherer, 04.12.2002, EP 02/406055.

  6. Verfahren zur Herstellung einer B/N/C/Si-Keramik aus einem Borazinprecursor, nach diesem Verfahren hergestellte Keramik sowie Verwendung der nach diesem Verfahren hergestellten Keramik, R. Nesper, J. Haberecht, H. Grützmacher, 03.04.2003, 0149/03.; EP 04707180.8-1218-CH2004000052.

  7. Process for preparing acylphosphanes and derivatives thereof, H. Grützmacher, J. Geier, D. Stein, M. Scherer, H. Schönberg, S. Boulmaâz, J.-P. Wolf, R. Sommerlade, CO 2/22920 18.07.2003; PCT Int. Appl. 2005, WO 2005014605.

  8. Process for preparing acylphosphanes and derivatives thereof, P. Murer, J.-P. Wolf, S. Burkhardt, H. Grützmacher, D. Stein, K. Dietliker, PCT Int. Appl. 2006, WO 2006/06541 A1.

  9. Verfahren zur Herstellung von Phosphorverbindungen, H. Grützmacher, E. Piras, DE 10320261, 27.04. 2003, Eur. Pat. Appl. 2004, EP 1475384.

  10. Tropylidenamine und deren Verwendung, H. Grützmacher, T. Büttner, P. Maire, M. Ramseier, D. Scheschkewitz, T. Zweifel, DE 102004027771, 2004; Eur. Pat. Appl. 2005, EP 05011539.3.

  11. Bistropylidendiamine und deren Verwendung, H. Grützmacher, P. Maire, DE 102004027772, 2004, Eur. Pat. Appl.2005, EP 05011538.5-2103.

  12. Übergangsmetallkatalysatoren, H. Grützmacher, E. Piras, F. Läng, DE 102005062363.8, 2005.

  13. Polymer Nanoparticles, T. Ott, H. Grützmacher, CH 0618/09; 20.4.2009.

  14. Polymer-bound bisacylphosphine oxides, H. Grützmacher, T. Ott, K. Dietliker, PC/PO-24010, 2009.

  15. Ultra fast process for the preparation of polymer nanoparticles, P. Seeberger, P. Laurino, K. Tauer, J. Bräuer, H. Grützmacher, EP 10013761; 2010.

  16. Process for the modification of polymer nanoparticles, P. Seeberger, P. Laurino, K. Tauer, J. Bräuer, H. Grützmacher, EP10013760; 2010.

  17. A Process for the preparation of Acylphosphanes, (Michael-Addition vom Na-Phosphid), H. Grützmacher, G. Müller, ETH T-12-040, EP12006822; 2012, WO 2014/053455 A1, US 9,701,700 B2.

  18. Derivatives of bisacylphosphinic acid, their preparation and use as photoinitiators, G. Müller, H. Grützmacher, K. Dietliker 74211 EP/US, 2012, WO 2014/095724 A1.

  19. A novel cross-linker for the preparation of a new family of single ion conduction polymers for electrochemical devices and such polymers, J.A. Gonzalez Martinez, M. Trincado-Rodriguez-Pick, H. Grützmacher, 2014, EP 3031798 A1

  20. Heptaphosphorus-derived compounds as flame retardants, R. Krämer, P. Deglmann, A. König, R. von Benten, A. Eisenhardt, S. Menon, F. Reuter, A. Tondreau, H. Grützmacher, 2014, WO 2015/144667.

  21. A versatile process for the preparation of acylphosphines, H. Grützmacher, P. Pringle, M. Bispinghoff, 2016, WO2018/050901.

  22. Novel photo-initiators and their application, A. Beil, M. Bispinghoff, H. Grützmacher, EP18161824.0.

  23. Novel vinyl phosphines and photo-initiators obtainable therefrom, M. Bispinghoff, H. Grützmacher, WO 2019/175319 A1.