张伟雄

教授

电子邮件

zhangwx6@mail.sysu.edu.cn

基本情况

姓名：张伟雄

性别：男

出生年月：1981-11

籍贯：广东梅州

职位：教授，博士生导师

联系方式

邮箱：zhangwx6@mail.sysu.edu.cn

通讯地址：广州市番禺区小谷围街道中山大学东校区化学材料综合楼

邮编：510006

教育经历

2004.09—2009.06：中山大学，无机化学专业硕博连读，博士

2000.09—2004.06：中山大学，应用化学专业，学士

工作经历

2018.04至今：中山大学化学学院，教授
2012.08—2018.04：中山大学化学学院，副教授
2010.06—2012.08：日本东北大学，日本学术振兴会（JSPS）博士后
2009.07—2010.06：中山大学化学学院，科研助理

讲授课程

无机化学
功能配位化学
高等无机化学

科研方向

多离子杂化晶体组装及其新材料开发。兼合“有机阳离子-无机阳离子-阴离子”定向设计与可控组装，发展离子间协同调控方法开发多离子集成材料。前期主攻高性能杂化铁电体、易加工玻璃陶瓷倍频材料等，期间发现并系统研究高能、稳定、易规模化制备、具有重大军民两用潜力的多离子集成含能材料（如高氯酸铵三乙烯二铵DAP-4）；通过建立其“赋能创制 - 按需调控 - 应用转化”全链条研究体系，为含能材料研究领域开辟了新方向。以第一发明人获国内外授权发明专利20余件；已发表论文160余篇，引用~1.2万次，H指数58。 Researcher ID: D-3365-2011 (https://www.webofscience.com/wos/author/record/D-3365-2011)

科研项目

国家自然科学基金叶企孙联合基金重点项目，U2341287，2024-2027
国家自然科学基金优青项目，21722107，2018-2020
国家自然科学基金面上项目，22071273，2021-2024
国家自然科学基金面上项目，21671202，2017-2020
国家自然科学基金青年项目，21301198，2014-2016

获奖情况

2020日本化学会杰出报告奖（Distinguished Lectureship Awards）
2016 广东省特支计划科技创新青年拔尖人才
2016 广州市珠江科技新星

论著一览

部分论文目录（* 表示通讯联系人）

2025年

Han D.-C.; Chen S.; Fan Y.-N.; Fang Z.-L.; Liang Y.-P.; Zhang W.-X.*
Modulating alkyl groups in hybrid quaternary ammonium salts to design polar glass-ceramic with strong nonlinear optical response
Sci. China Chem.2025, DOI: 10.1007/s11426-024-2542-3.
Yu C.-X; Ye L.; Zhuo H.; Yan Y.-F.; Zhang W.-X.*
Barium(II)-based molecular perovskite energetic compounds for next-generation pyrotechnic materials
Inorg. Chem. Front. 2025, DOI: 10.1039/D5QI00442J

Ye L.; Fang Z.-L.; Guo M.-Y.; Zhang W.-X.*
Hot-pressing boosted nonlinear optical properties in a new ferroelectric plastic crystalline material
Chin. Chem. Lett.2025, DOI: 10.1016/j.cclet.2025.110826.
Li X.-X.; Ren P.; Wu R,; Wang Y,; Deng P.; Han K.-H.; Shang Y.; Chen S.-L.*; Zhang W.-X.*
An alternative ignition agent concept based on ionic integrated energetic oxidant
Chem. Eng. J.2025, 510, 161489.

2024年

Li Y.-B.; Chen X.-X.; Xu W.-J.; Gong Y.-P.; Ye H.; Wang Z.-S.; Zhang W.-X.*
Designing dynamic coordination bonds in polar hybrid crystals for a high-temperature ferroelastic transition
Chem. Sci. 2024, 15, 3661.
Li Y.-B.; Xu W.-J.*; Chen X.-X.; Liu D.-X.; Wang Z.-S.; Zhang W.-X.*
Switchable K–O bonds unveiling anomalous ferroelastic transitions in a polar hybrid crystal
Sci. China Mater. 2024, 67, 3408.
Li M.-F.; Guo M.-Y.; Liu D.-X.; Chen X.-X.; Xu W.-J.*; Zhang W.-X.*
Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]
Chin. Chem. Lett. 2024, 35, 109507.
Guo M.-Y.; Li M.-F.; Chen X.-X.; Xu W.-J.*; Zhang W.-X.*
Equatorial−axial conformational dynamics enabling thermoresponsive SHG switch in a homochiral hybrid compound
ACS Appl. Opt. Mater.2024, 2, 2612.
Chen S.; Han D.-C.; Ye L.; Zhang W.-X.*
Three-step ferroelastic transitions from hexagonal to triclinic phases in a hybrid perovskite: (1-fluoromethyl-1-methylpyrrolidine)[CdCl₃]
Inorg. Chem.2024, 63, 7966.
Yu C.-X.; Ye L.; Fang Z.-L.; Zhang W.-X.*; Chen X.-M.
Synthesis, structure, and properties of a new molecular perovskite energetic material: triethylenediammonium ammonium chlorate
Chin. J. Energ. Mater. 2024, 32, 1014.

2023年

Liu D.-X.; Zhu H.-L.; Zhang W.-X.*; Chen X.-M.
Nonlinear optical glass-ceramic from a new polar phase-transition organic-inorganic hybrid crystal
Angew. Chem. Int. Ed. 2023, 62, e202218902.
Xu W.-J.; Li M.-F.; Garcia A.; Romanyuk K.; Martinho J.; Zelenovskii P.; Tselev A.; Verissimo L.; Zhang W.-X.*; Chen X.-M.; Kholkin A.*; Rocha J.*
Molecular design of a metal-nitrosyl ferroelectric with reversible photoisomerization
J. Am. Chem. Soc. 2023, 145, 13663.
Zhao B.-Q.; Chen X.-X.; Ye H.; Gong Y.-P.; Wang J.; Ye L.; Zhang W.-X.*
An anomalous ferroelastic phase transition arising from an unusual cis-/anti-conformational reversal of polar organic cations
Chem. Sci. 2023, 14, 5965.
Yu Z.-H.; Liu D.-X.; Ling Y.-Y.; Chen X.-X.; Shang Y.; Chen S.-L.; Ye Z.-M.; Zhang W.-X.*; Chen X.-M.
Periodate-based molecular perovskites as promising energetic biocidal agents
Sci. China Mater. 2023, 66, 1641.
Wang J.; Chen X.-X.; Ye L.; Gong Y.-P.; Shang Y.; Zhang W.-X.*
A room-temperature moisture-stabilized metal-free energetic ferroelectric material for piezoelectric generation
Mater. Chem. Front.2023, 7, 2251.
Liu D.-X.; Yu Z.-H.; Chen X.-X.; Zhang W.-X.*; Chen X.-M.
Crystal structures and phase transitions in two new hybrid crystals: (Me₃NCH₂CH₂X)₄[Ni(NCS)₆] (X = Cl and Br)
Chin. Chem. Lett. 2023, 34, 107310.
Gong Y.-P.; Chen X.-X.; Zhao B.-Q.; Wang J.; Zhang W.-X.*; Chen X.-M.
Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)
Chin. Chem. Lett.2023, 34, 108282.

2022年

Zeng Y.; Hu C.-L.; Xu W.-J.; Zeng T.-W.; Zhu Z.-X.; Chen X.-X.; Liu D.-X.; Chen Y.-J.; Zhang Y.-B.; Zhang W.-X.*; Chen X.-M.
An exceptional thermally-induced four-state nonlinear-optical switch arising from stepwise molecular dynamic changes in a new hybrid salt
Angew. Chem. Int. Ed. 2022, 61, e202110082.
Ye H.; Chen X.-X.; Liu D.-X.; Zhao B.-Q.; Li Y.-B.; Zeng Y.; Zhang W.-X.*; Chen X.-M.
Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic
Chem. Sci. 2022, 13, 14124.
Gong Y.-P.; Chen X.-X.; Huang G.-Z.; Zhang W.-X.*; Chen X.-M.
Ferroelasticity, thermochromism, semi-conductivity, and ferromagnetism in a new layered perovskite: (4-fluorophenethylaminium)₂[CuCl₄]
J. Mater. Chem. C 2022, 10, 5482.
Liu D.-X.; Chen X.-X.; Ye Z.-M.; Zhang W.-X.*; Chen X.-M.
High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me₃NCH₂CH₂OH)₄[Ni(NCS)₆]
Sci. China Mater. 2022, 65, 263.
Chen X.-X.; Liu D.-X.; Gong Y.-P.; Wang S.-S.; Zhang W.-X.*; Chen X.-M.
Above-room-temperature ferroelastic phase transitions in two tetrafluoroborate-based hexagonal molecular perovskites
Inorg. Chem. 2022, 61, 2219.
Shang Y.; Chen S.-L.*; Yu Z.-H.; Huang R.-K.; He C.-T.; Ye Z.-M.; Zhang W.-X.*; Chen X.-M.
Silver(I)-based molecular perovskite energetic compounds with exceptional thermal stability and energetic performance
Inorg. Chem. 2022, 61, 4143.
Huang B.; Wang P.; Zhang W.-X.*; Chen X.-M.
Magnetic-dielectric bistabilities and magnetodielectric coupling effects in a new layered hybrid perovskite: (C₆H₅(CH₂)₄NH₃)₂[MnCl₄]
Mater. Adv. 2022, 3, 9103.
Chen S.-L.*; Shang Y.; Jiang J.; Huang M.; Ren J.-T.; Guo T.; Yu C.-X.; Zhang W.-X.*; Chen X.-M.
A new nitrate-based energetic molecular perovskite as a modern edition of black powder
Energ. Mater. Front. 2022, 3, 122.
Shang Y.; Sun L.-Y.; Ye Z.-M.; Chen S.-L.*; Zhang W.-X.*; Chen X.-M.
Phase transition and thermal expansion of molecular perovskite energetic crystal (C₆N₂H₁₄)(NH₄)(ClO₄)₃ (DAP-4)
FirePhysChem 2022, 2, 221.

2021年

Chen X.-X.; Zhang X.-Y.; Liu D.-X.; Huang R.-K.; Wang S.-S.; Xiong L.-Q.; Zhang W.-X.*; Chen X.-M.
Room-temperature ferroelectric and ferroelastic orders coexisting in a new tetrafluoroborate-based perovskite
Chem. Sci. 2021, 12, 8713.
Meng Q.-R.; Xu, W.-J.; Hu W.-H.; Ye H.; Chen X.-X.; Yuan, W.; Zhang W.-X.*; Chen X.-M.
An unprecedented hexagonal double perovskite organic–inorganic hybrid ferroelastic material: (piperidinium)₂[KBiCl₆]
Chem. Commun. 2021, 57, 6292.
Jia Z.-H.; Liu J.-Y.; Liu D.-X.; Zhang S.-Y.; Du Z.-Y.*; He C.-T.*; Zhang W.-X.*; Chen X.-M.
Four-step thermosensitive dielectric response arising from motionable low-symmetry ammonium confined in deformable supramolecular cages
J. Mater. Chem. C 2021, 9, 8076.
Xu W.-J.; Romanyuk K.; Martinho J.; Zeng Y.; Ushakov A.; Shur V.; Tselev A.; Zhang W.-X.*; Chen X.-M., Kholkin A.*; Rocha J.*
Statics and dynamics of ferroelectric domains in molecular multiaxial ferroelectric (Me₃NOH)₂[KCo(CN)₆]
J. Mater. Chem. C 2021, 9, 10741.

2020年以前

Xu W.-J.; Romanyuk K.; Martinho J.; Zeng Y.; Zhang X.-W.; Ushakov A.; Shur V.; Zhang W.-X.*; Chen X.-M.; Kholkin A.*; Rocha J.*
A photo-responsive organic-inorganic hybrid ferroelectric designed at molecular level
J. Am. Chem. Soc. 2020, 142, 16990.
Huang R.-K.; Wang S.-S.; Liu D.-X.; Li, X.; Song J.-M.; Xia Y.-H.; Zhou D.-D.*; Huang J.; Zhang W.-X.*; Chen X.-M.
Supercooling behavior and dipole-glass-like relaxation in a three-dimensional water framework
J. Am. Chem. Soc. 2019, 141, 5645.
Xu W.-J.; Li P.-F.; Tang Y.-Y.; Zhang W.-X.*; Xiong R.-G.; Chen X.-M.
A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
J. Am. Chem. Soc.2017, 139, 6369. (Highlighted in Science)
Li W.; He C.-T.; Zeng Y.; Ji C.-M.; Du Z.-Y.*; Zhang W.-X.*; Chen X.-M.
A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
J. Am. Chem. Soc. 2017, 139, 8086.
Shi Q.; Xu W.-J.; Huang R.-K.; Zhang W.-X.*; Li Y.; Wang P.-F.; Shi F.-N.*; Li L.-B.; Li J.-P.; Dong J.-X.*
Zeolite CAN and AFI-type ZIFs with large 12-MR pore openings synthesized using bulky amides as structure-directing agents
J. Am. Chem. Soc. 2016, 138, 16232.
Liu J.-Y.; Zhang S.-Y.; Zeng Y.; Shu X.; Du Z.-Y.*; He C.-T.*; Zhang W.-X.*; Chen X.-M.
Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Angew. Chem. Int. Ed. 2018, 57, 8032.
Du Z.-Y.; Xu T.-T.; Huang B.;Su Y.-J.; Xue W.; He C.-T.; Zhang W.-X.*; Chen X.-M.
Switchable guest molecular dynamics in a Perovskite-like coordination polymer toward sensitive thermo-responsive dielectric materials
Angew. Chem. Int. Ed. 2015, 54, 914.
Zhang S.-Y.^#; Shu X.^#; Zeng Y.^#; Liu Q.-Y.; Du Z.-Y.*; He C.-T.*; Zhang W.-X.*; Chen X.-M.
Molecule-based nonlinear optical switch with highly tunable on-off temperature using a dual solid solution approach
Nat. Commun. 2020, 11, 2752.
Xu W.-J.; He C.-T.; Ji C.-M.; Chen S.-L.; Huang Y.-K.; Lin R.-B.; Luo J.-H.; Zhang W.-X.*; Chen X.-M.
Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Adv. Mater. 2016, 28, 5886.
Shang Y.; Yu Z.-H.; Huang R.-K.; Chen S.-L.*; Liu D.-X.; Chen X.-X.; Zhang W.-X.*; Chen X.-M.
Metal-free hexagonal perovskite high-energetic materials with NH₃OH⁺/NH₂NH₃⁺ as B-site cations
Engineering 2020, 6, 1013.
Huang B.; Zhang J.-Y.; Huang R.-K.; Chen M.-K.; Xue W.; Zhang W.-X.*; Zeng M.-H.; Chen X.-M.
Spin-reorientation-induced magnetodielectric coupling effects in two layered perovskite magnets
Chem. Sci. 2018, 9, 7413.
Wang S.-S.; Chen X.-X.; Huang B.; Huang R.-K.; Zhang W.-X.*; Chen X.-M.
Unique freezing dynamics of flexible guest cations in the first molecular postperovskite ferroelectric: (C₅H₁₃NBr)[Mn(N(CN)₂)₃]
CCS Chem. 2019, 1, 448.
Zhang W.-X.*; Chen S.-L.; Shang Y.; Chen X.-M.*
Molecular perovskites as a new platform for designing advanced multi-component energetic crystals
Energ. Mater. Front. 2020, 1, 123 (invited review).
Chen S.-L.; Yang Z.-R.; Wang B.-J.; Shang Y.; Sun L.-Y.; He C.-T.; Zhou H.-L.; Zhang W.-X.*; Chen X.-M.*
Molecular perovskite high-energetic materials
Sci. China Mater. 2018, 61, 1123. (News Link: What else can molecular perovskite do?)

张伟雄