基本情况 

姓名:陈小明

性别:男

籍贯:暂未填写

职位:教授,博士生导师,现任生物无机与合成化学教育部重点实验室主任,2000年至2004年长江学者特聘教授。2009年当选中国科学院院士

联系方式 

电话:+86-020-84113986

传真:暂未填写

邮箱:cxm@mail.sysu.edu.cn

通讯地址:广州市新港西路中山大学化学与化学工程学院

邮编:510275

个人网站:http://ce.sysu.edu.cn/cxm/

教育经历

1983年获中山大学理学学士学位;
1986年获中山大学理学硕士学位;
1992年获香港中文大学哲学博士学位。

工作经历 

主要工作简历:
1986年至1989年在中山医科大学生物化学教研室工作,历任助教、讲师
19927月起在中山大学化学与化学工程学院工作
199312月晋升副教授,19951月晋升教授
2000年至2004年,长江学者特聘教授
2006年至今,生物无机与合成化学教育部重点实验室主任
主要学术兼职:

先后兼任生物无机与合成化学教育部重点实验室主任、中大化学院院长、中国晶体学会副理事长、中国科学院化学部常委及副主任、国家学位委员会化学学科评议组成员、国家基金委化学部专家咨询委员会成员、国际分子筛协会金属有机框架材料(MOF)委员会成员等职务等。

讲授课程 

主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程;指导博士后、博士生、硕士生以及国内访问学者的科研工作。

科研方向 

功能配位化学与晶体工程研究,特别是配位聚合物、金属有机框架材料等的设计与合成、结构与功能(吸附与分离、催化、光电磁、传感)研究,以及含能分子晶体研究。 

科研项目

暂无资料

获奖情况

2007  国家自然科学奖二等奖(第一完成人):配合物控制合成与晶体工程方法基础研究
2008  汤森路透卓越研究奖 (Thomson Reuters   Research Fronts Award)
2012  发展中国家科学院TWAS化学奖
2012  广东省科学技术奖一等奖(第一完成人): “微孔与磁性配位聚合物研究
2014  汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2015  汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2016  汤森路透高被引用科学家 (Thomson Reuters Highly Cited Researcher)
2017  科睿唯安高被引用科学家 (Clarivate Highly Cited Researcher)
2017  广东省科学技术奖突出贡献奖

论著一览

编写教材: 
《单晶结构分析原理与实践》(与蔡继文博士合作),科学出版社,20039月第一版,20078月第二版。 

陈小明在国际刊物发表的部分论文目录:
Selected Publications of Xiao-Ming Chen:

 1Polynuclear CuII12-MIII6 (M = Y, Nd or Gd) complexes encapsulating a ClO4 anion:
[Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601. PDF

2Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N. Angew. Chem. Int. Ed. 1999, 38, 2237-2240. PDF

3Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031. PDF

4A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883. PDF

5(Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202. PDF

6Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209.

7A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219. PDF

8(Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565. PDF

9Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506. PDF

10Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082. PDF

11Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163. PDF

12Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559. PDF

13Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314. PDF

14(Review Article) Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170. PDF

15A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498. PDF

16A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China) PDF

17Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739. PDF

18Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538. PDF

19Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017; PDF

20Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2009, 131, 5516–5521. (Highlighted in Nature China) Link.

21(Review Article) Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M., Chem. Soc. Rev. 2009, 38, 2385–2396. Link

22A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2009, 48, 5287-5290. Link.

23Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2010, 132, 6654–6656. Link

24Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M., Adv. Mater. 2011, 22, 1268–1271. PDF

25A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2011, 2, 2214-2218. Link.

26Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2012, 3, 642. DOI: 10.1038/ncomms1654. Link

27(Review Article) Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M., Chem. Rev. 2012, 112, 1001–1033. Link

28Strong and dynamic CO2 sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2012, 134, 17380-17383. Link

29A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 351–356. Link

30Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 1539-1546. Link

31Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2013, 4, 2534. DOI: 10.1038 /ncomms3534. Link

32A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.; Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2013, 52, 13429-13433. Link

33(Invited Review) Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M., Chem. Soc. Rev. 2014, 43, 5789-5814. DOI: 10.1039/C4CS00129J. Link

34Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M., Adv. Funct. Mater. 2014, 24, 5866–5872. DOI: 10.1002/adfm.201401125. Link

35Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen, Chem. Sci. 2014, 5, 4755. DOI: 10.1039/C4SC01505C. Link

36Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming; Angew. Chem. Int. Ed. 2015, 54, 914 –918. DOI: 10.1002/anie.201408491. Link

37Monodentate hydroxide as a super strong yet reversible active site for CO2 capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting; Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen, Energy Environ. Sci. 2015, 8, 1011-1016. DOI: 10.1039/C4EE02717E. Link

38Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.; Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6350. doi:10.1038/ncomms7350. Link

39. Tuning fluorocarbon adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2015, 6, 2516-2521. DOI: 10.1039/C4SC03985H. Link

40Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6917. DOI: doi: 10.1038/ncomms7917. Link

41(Invited Review) Metal cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen, Coord. Chem. Rev. 2015, 293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009. Link 

42Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna, Rajamani; Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2015, 137, 7217–7223. Link

43Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8348. DOI: 10.1038/ncomms9348. Link

44Efficient purification of ethene by ethane-trapping metal-organic framework 
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8697. doi:10.1038/ncomms9697. Link

45(Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 4674–4678. DOI: 10.1002/anie.201511006. Link

46An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei; Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming, J. Am. Chem. Soc. 2016, 138, 8336–8339. DOI: 10.1021/jacs.6b03125. Link

47Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming; Adv. Mater., 2016, 28, 5886–5890. DOI: 10.1002/adma.201600895. Link

48(Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO2
Kai-Jie Chen, David G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko, Angew. Chem. Int. Ed. 2016, 55, 10268–10272. DOI: 10.1002/anie.201603934. Link

49Putting ultrahigh concentration of amine groups into a metal–organic framework for CO2 capture at low pressures
Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong; Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci. 2016, 7, 6528-6533. DOI:  10.1039/C6SC00836D. Link

50Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 6021–16025. DOI: 10.1002/anie.201608439. Link

51Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 1778–1781. DOI: 10.1021/jacs.6b12353. Link

52. A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan; He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 139, 5285–5288. DOI: 10.1021/jacs.7b00165. Link

53A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 6369–6375. DOI: 10.1021/jacs.7b01334. Link

54Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Science, 2017, 356, 1193-1196. DOI: 10.1126/science.aam7232. Link

55A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi; Zhang, Wei-Xiong;  Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 8086–8089. DOI: 10.1021/jacs.7b02981. Link

56Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2017, 8, 7560–7565. DOI: 10.1039/c7sc03067c. Link

57Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO2 reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng; J. Am. Chem. Soc. 2018, 140, 38–41. Link

58Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long; Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming, Zhang, Jie-Peng; Adv. Mater. 2018, 30, 1704350.  adma.201704350. Link

59Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu, Xia; Du, Zi-Yi; He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2018, 10.1002/anie.201802580. Link

相关成果

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