2018年10月29日徐强教授学术报告

Metal-organic frameworks for catalysis and energy

发布人:程萍 发布日期:2018-10-26
主题
Metal-organic frameworks for catalysis and energy
活动时间
-
活动地址
丰盛堂芙兰学术中心A402
主讲人
徐强教授
主持人
李光琴教授

报告摘要:

There has been a rapid development in metal-organic frameworks (MOFs), especially porous MOFs, due to their high potential for diverse applications in the past decade, especially for catalysis and energy. Recently, we have successfully synthesized a number of new porous MOFs and found their new applications as catalysts, as supports for metal nanoparticles and as templates/precursors for nanoporous carbon synthesis.1-2 Novel porous metal-organic frameworks have been synthesized, which present stable catalytic activities for the oxidation of CO to CO2. Metal nanoparticles (NPs) have been immobilized to MOFs by the solid-grinding method, impregnation method and double-solvents approach in combination with the H2 reduction, liquid-phase concentration-controlled reduction and the CO-directed reduction at the solid-gas interface, which exhibit excellent catalytic performances for various reactions, including hydrogen generation from chemical hydrides. “Quasi-MOFs” have been prepared by controlled deligandation of MOFs, which have a transition-state structure between the porous MOFs and metal oxides. The metal cluster/quasi-MOF composites not only retain a porous structure but also achieve a strong interaction between the metal clusters (eg, Au) and the inorganic nodes (eg, Cr–O) of the quasi-MOF, leading to dramatically enhanced catalytic performance in the low-temperature oxidation of carbon monoxide (CO). Porous carbons have been synthesized by using MOFs as templates/precursors and the resultant carbons display high specific surface areas and excellent electrochemical properties as electrode materials for electric double-layered capacitor (EDLC) and as catalysts for oxygen reduction reaction (ORR). This talk will discuss the catalytic and energy applications of MOFs.

报告人简介:

徐强教授于1994年在大阪大学获得博士学位,目前是AIST-京都大学化学能源材料开放创新实验室(ChEM-OIL)主任,同时也是扬州大学特聘教授,神户大学和京都大学的兼职教授,香港理工大学荣誉杰出教授。他于2012年获得汤姆森路透社前沿研究奖,在2014-2018年连续被汤姆森路透社评为化学、工程和材料科学方面高被引科学家。主要从事化学相关的纳米材料及其应用研究,目前已经发表了超过300篇研究论文,总被引次数超过23000次,h指数大于80。 他目前还担任多个杂志的编辑和编委,如EnergyChem(Elsevier)的主编,Coordination Chemistry Reviews(Elsevier)的副主编,以及Chem(Cell Press),Chemistry-an Asian Journal(Wiley)和Advanced Sustainable Systems(EurASc)的编委,同时徐强教授还是欧洲科学院院士(EurASc),印度国家科学院院士,英国皇家化学学会会士。