陈小明教授简介

陈小明教授简介

基本情况

姓名:陈小明

性别:男

籍贯:暂未填写

职位:

教授,博士生导师,现任生物无机与合成化学教育部重点实验室主任,2000年至2004年长江学者特聘教授。2009年当选中国科学院院士

联系方式

电话:+86-020-84113986

传真:暂未填写

邮箱:cxm@mail.sysu.edu.cn

通讯地址:广州市新港西路中山大学化学与化学工程学院

邮编:510275

个人网站:http://ce.sysu.edu.cn/cxm/

教育经历

1983年获中山大学理学学士学位;
1986年获中山大学理学硕士学位;
1992年获香港中文大学哲学博士学位。

工作经历

主要工作简历:
1986年至1989年在中山医科大学生物化学教研室工作,历任助教、讲师
1992年7月起在中山大学化学与化学工程学院工作
1993年12月晋升副教授,1995年1月晋升教授
2000年至2004年,长江学者特聘教授
2006年至今,生物无机与合成化学教育部重点实验室主任
主要学术兼职:
国务院学位委员会第六届学科评议组成员;中国晶体学会副理事长、中国化学会理事、中国稀土学会理事;
《无机化学学报》副主编,以及《中国科学:化学》、 《结构化学》、《中国稀土学报》、《中国化学》和《高等学校化学学报》编委;
Advisory Board Member of Chemcal Communications (RSC) ,CrystEngComm. (RSC); Topic Editor of Crystal Growth & Design (ACS), International Advisory Board Member of European Journal of Inorganic Chemistry (Wiley), Editorial Board Member of Polyhedron (Elsevier).

讲授课程

主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程;指导博士后、博士生、硕士生以及国内访问学者的科研工作。

科研方向

功能金属配合物和聚合金属配合物超分子体系的分子设计、合成和结构与性能研究,重点在微孔配位聚合物、磁性配位聚合物、动态配位聚合物以及发光化合物的合成化学与晶体工程研究。

科研项目

暂无资料

获奖情况

曾作为第一完成人获国家自然科学奖二等奖一项和广东省自然科学奖一等奖两项,并先后获得香港求是科技基金会“杰出青年学者奖”、第五届“中国青年科技奖”,以及教育部“全国优秀教师”等个人奖励。
1993年以来,主持国家杰出青年科学基金、国家基金委员会重点项目和国家973计划等国家和省部级等20余项科学基金课题。
作为通讯联系人在包括美国 J. Am. Chem. Soc., Inorg. Chem., Organometallics, Cryst. Growth Des.,德国 Angew. Chem., Adv. Mater., Chem. Eur. J., Eur. J. Inorg. Chem.,英国 Chem. Commun., Dalton Trans., J. Mater. Chem., New J. Chem. 和 CrystEngComm 等国内外刊物发表200多篇论文;
应邀在 Acc. Chem. Res., Coord. Chem. Rev. 等刊物发表综述5篇,为 John Wiley 出版的专著 Frontiers in Crystal Engineering 撰写一章。

论著一览

编写教材:
《单晶结构分析原理与实践》(与蔡继文博士合作),科学出版社,2003年9月第一版,2007年8月第二版。
近年作为通讯作者发表的部分论文目录:
2009
1. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal Zhang, J.-P.; Chen, X.-M.J. Am. Chem. Soc. 2008, ja-2008-089872.
2. Two metal-carboxylate frameworks featuring uncommon 2D + 3D and 3-fold interpenetration: (3,5) connected isomeric hms and gra nets Hou, L.; Zhang, J.-P.; Chen, X.-M.Cryst. Growth Des.  2009, cg-2008-01308u
3. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties Zhu, A.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Inorg. Chem. 2009, ic-2008-02446m.
4. A spin-frustrated complex, [FeIIFeIII(trans-1, 4-cyclohexanedicarboxylate)1.5]∞: Interplay between single-chain magnet behavior and magnetic ordering Zheng, Y.-Z.; Xue,  W.; Zhang, W.-X.; Tong, M. L.; Chen, X.-M.; Grandjean F.; Long G. J.; Ng, S. W.; Panissod P.; Drillon M., Inorg. Chem. 2009, 48, 2028–2042.
5. Syntheses, structures and magnetic properties of a family of metal carboxylate polymers via in-situ metal/ligand reactions of benzene-1,2,3-tricarboxylic acid Zheng, Y.-Z.; Zhang, Y.-B.; Tong, M.-L.; Xue W.; Chen, X.-M.; Dalton Trans 2009, 1396-1406.
6. Syntheses, structures and sorption properties of two framework-isomeric porous copper coordination polymers Xue D.-X.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M.CrystEngComm 2009, 11, 183-188.
2008
7. Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues Zheng, Y.-Z.; Xue, W.; Tong, M.-L.; Chen, X.-M.; Zheng, S.-L., Inorg. Chem. 2008, 47, 11202–11211.
8. Microwave-assisted solvothermal synthesis of a dynamic nanoporous metal-carboxylate framework Wang, X.-F.; Zhang, Y.-B.; Huang, H.; Zhang, J.-P.; Chen, X.-M.Cryst. Growth Des. 2008, 8, 4559-4563.
9. Pillaring Zn-triazolate layers with flexible aliphatic dicarboxylates into three-dimensional metal-organic frameworks Lin, Y.-Y.; Zhang, Y.-B.; Zhang, J.-P.; Chen, X.-M., Cryst. Growth Des. 2008, 8, 3673–3679.
10. (Hot Paper) Assembly of 3D geometrically frustrated magnets with tranistion metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes Zhang, W.-X.; Xue, W.; Lin, J.-B.; Zheng, Y.-Z.; Chen, X.-M.CrystEngComm 2008, 10, 1770-1776.
11. Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters Hou, L.; Zhang, J.-P.; Chen, X.-M.; Ng, S.W., Chem. Commun. 2008, 4019–4021.
12. Weak ferromagnetism and dynamic magnetic behaviors of two 2D compounds with hydroxy/carboxylate-bridged Co(II) chains Cheng, X.-N., Xue, W., Zhang, W.-X., Chen, X.-M.Chem. Mater. 2008, 20, 5345–5350.
13. Pentanuclear and heptanuclear metal helicates by self-assembly of d10 metal ions and a rigid aromatic bis-bidentate chelator Zhu, A.-X., Zhang, J.-P., Lin, Y.-Y., Chen, X.-M., Inorg. Chem. 2008, 47, 7389-7395..
14. Two microporous metal-organic frameworks with different topologies constructed from linear trinuclear M3(COO)n secondary building units Wang, X.-F., Zhang, Y.-B., Cheng, X.-N., Chen, X.-M.CrystEngComm 2008, 10, 753–758.
15. A two-dimensional iron(II) carboxylate linear chain polymer that exhibits a metamagnetic spin-canted antiferromagnetic to single-chain magnetic transition Zheng, Y.-Z., Xue, W., Tong, M.-L., Zhang, W.-X., Chen, X.-M., Grandjean F.; Long G. J., Inorg. Chem. 2008, 47, 4077-4087.
16. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework Zhang, J.-P.; Chen, X.-M.J. Am. Chem. Soc. 2008, 130, 6010–6017.
17. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials Zheng, Y.-Z.; Xue W.; Zheng, S.-L.; Tong, M.-L. ; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538.
18. Single-crystal-to-single-crystal transformation involving release of bridging water molecules and transform of chain helicity in a chiral three-dimensional metal-organic framework Xue, D.-X.; Zhang, W.-X.; Chen, X.-M.; Wang, H.-Z.,Chem. Commun. 2008, 1551-1553.
19. Porous metal-organic framework based on μ4-oxo tetrazinc clusters: sorption and guest-dependent luminescent properties Hou, L.; Lin, Y.-Y.; Chen, X.-M.Inorg. Chem. 2008, 47, 1346-1351.
2007
20. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin canting antiferromagnetic layer Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M.J. Am. Chem. Soc. 2007, 129, 15738-15739.
21. Rational construction and hydrogen storage behavior of a dynamic microporous metal-organic framework with BCT zeolite topology, Hu, S.; Zhang, J.-P.; Tong, M.-L.; Chen, X.-M.Kitagawa, S. Cryst. Growth Des. 2007, 7, 2286-2289.
22. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China)
23. From pseudo to true C3-symmetry: Magnetic anisotropy enhanced by site-specific ligand substitution in two Mn15-carboxylate clusters Zheng, Y.-Z.; Zhang, W.-X.; Xue, W.; Tong, M.-L.; Chen, X.-M.Inorg. Chem. 2007, 46, 6437-6443.
24. A tetracarboxylate–bridged dicopper(II) paddle-wheel-based 2-D porous coordination polymer with gas sorption properties Xue, D.-X; Lin, Y.-Y.; Cheng, X.-N.; Chen, X.-M.Cryst. Growth Des. 2007, 7, 1332-1336.
25. Unprecedented (3,9)-connected (42.6)3(46.621.89) net constructed by trinclear mixed-valence cobalt clusters Zhang, X.-M.; Zheng, Y.-Z.; Li, C.-R.; Zhang, W.-X.; Chen, X.-M.Cryst. Growth Des. 2007, 7, 980–983.
26. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M.Adv. Mater. 2007, 19, 1494–1498.
27. Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170.
28. In situ solvothermal generation of 1,2,4-triazolates and related compounds from organonitriles and hydrazine hydrate: A mechanism study Cheng, L.; Zhang, W.-X.; Ye, B.-H.; Lin, J.-B.; Chen, X.-M.Inorg. Chem. 2007, 46, 1135-1143.
2006
29. Encapsulation of water cluster, meso-helical chain and tapes in metal-organic frameworks based on double-stranded Cd(II) helicates and carboxylates Cheng, L.; Lin, J.-B.; Gong, J.-Z.; Sun, A.-P.; Ye, B.-H.; Chen, X.-M.Cryst. GrowthDes. 2006, 6, 2739-2746.
30. A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties Zeng, M.-H.; Feng, X.-L.; Zhang, W.-X.; Chen, X.-M.Dalton Trans. 2006, 5294-5303.
31. Chiral magnetic metal-organic frameworks of dimetal sub-units: Magnetism tuning by mixed-metal compositions of the solid solutions Zeng, M.-H.; Wang, B.; Wang, X.-Y.; Zhang, W.-X.; Chen, X.-M., Gao, S. Inorg. Chem. 2006, 45, 7069-7076.
32. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M.Angew. Chem. Int. Ed. 2006, 45, 6310-6314.
33. The slow magnetic relaxation observed in a mixed carboxylate/hydroxide-bridged compound [Co2Na(4-cpa)2(m3-OH)(H2O)]¥ featuring spin-frustrated magnetic D-chains Cheng, X.-N.; Zhang, W.-X.; Zheng, Y.-Z.; Chen, X.-M.Chem. Commun. 2006, 3603-3605.
34. Syntheses, structures and photoluminescence of three coordination polymers of cadmium dicarboxylates Zhang, L.-Y.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Cryst. Growth Des. 2006, 6, 1684-1689.
35. Solvent-induced supramolecular isomerism in silver(I) 2-methylimidazolate Huang, X.-C.; Li, D.; Chen, X.-M.,CrystEngComm 2006, 8, 351-355.
36. One-dimensional supramolecular isomerism of copper(I) and silver(I) imidazolates based on the ligand orientations Huang, X.-C.; Zhang, J.-P.; Chen, X.-M.Cryst. Growth Des. 2006, 6, 1194-1198.
37. (Feature Article) Crystal engineering of binary metal imidazolate and triazolate frameworks Zhang, J.-P.; Chen, X.-M.Chem. Commun. 2006, 1689-1699.
38. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M.Angew. Chem. Int. Ed. 2006, 45, 1557-1559.
39. From one- to three-dimensional architectures: Supramolecular isomerism of copper(I) 3,5-di(4-pyridyl)-1,2,4-triazolate involving in situ ligand synthesis Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M.Cryst. Growth Des. 2006, 6, 519–523.
40. Coexistence of spin frustration and long-range magnetic ordering in a triangular CoII3(m3-OH)-based two-dimensional compound Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M.Chem. Commun. 2006, 165–167.
2005
41. Synthesis, structures, magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd or Tb) complexes He, F.; Tong, M.-L.; and Chen, X.-M.Inorg. Chem. 2005, 44, 8285-8292.
42. Supramolecular isomerism within three-dimensional 3-connnected nets: Unusual synthesis and characterization of trimorphic copper(I) 3,5-dimethyl-1,2,4-triazolate Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M.Dalton Trans.2005, 3681-3685.
43. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163.
44. Infinite water chains trapped in organic framework constructed from melamine with 1,5-naphthalenedisulfonic acid via hydrogen bonds Zhang, X.-L.; Ye, B.-H.; Chen, X.-M.Cryst. Growth Des. 2005, 5, 1609-1616.
45. Syntheses, structures, photoluminescence and theoretical studies of a class of Be(II) compounds of aromatic N,O-chelate ligands Tong, Y.-P.; Zheng, S.-L.; Chen, X.-M.Inorg. Chem. 2005, 44, 4270-4275.
46. A solvothermally in-situ generated mixed-ligand approach for NLO-active metal–organic framework materials Wang, Y.-T.; Fan, H.-H.; Wang, H.-Z.; Chen, X.-M., Inorg. Chem. 2005, 44, 4148-4149.
47. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets Zeng, M.-H.;Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M.,Angew. Chem. Int. Ed. 2005, 44, 3079-3082.
48. Well-resolved, new water morphologies obtained by modification of the hydrophilic/hydrophobic characters and shapes of the supporting surfaces Zhang, J.-P.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Inorg. Chem. 2005, 44, 3146-3150.
49. Luminescent zigzag chains and triple-stranded helices of copper(I) 2-ethylimidazolate: Solvent polarity-induced supramolecular isomerism Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M.Chem. Commun. 2005, 2232–2234.
50. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M.J. Am. Chem. Soc. 2005, 127, 5495-5506.
51. Effect of the size of aromatic chelate ligands on the frameworks of metal dicarboxylate polymers: from helical chains to 2-D networks Han, Z.-B.; Cheng, X.-N.; Chen, X.-M.Cryst. Growth Des. 2005, 5, 695–700.
52. Supramolecular architectures and helical water chains in cocrystals of melamine and aromatic carboxylic acids Zhang, X.-L.; Chen, X.-M., Cryst. Growth Des. 2005, 5, 617-622.
53. Molecular chairs, zippers, zigzag and helical chains: chemical enumeration of supramolecular isomerism based on a predesigned metal-organic building-block Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., Chem. Commun. 2005, 1258–1260. (Hot Paper)
54. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands Ye, B.-H.; Tong, M.-L.; Chen, X.-M.Coord. Chem. Rev. 2005, 249, 545–565.
55. Controlled assembly of nanoscale heterometallic Cu12Ln6 Clusters (Ln = GdIII or NdIII) into 2D coordination polymers He, F.; Tong, M.-L.; Yu, X.-L.; Chen, X.-M.Inorg. Chem. 2005, 44, 559-565.
56. Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure? Wang, Y.-T.; Tong, M.-L., Fan, H.-H.; Wang, H.-Z.; Chen, X.-M.Dalton Trans. 2005, 424-426. (Hot Paper, Highlighted in Chemical Science)
57. Metallophilicity versus p-p interactions: Ligand-unsupported argentophilicity/cuprophilicity in oligomers-of-dimers [M2L2]n (M = CuI or AgI, L = tridentate ligand) Zhang, J.-P.; Wang, Y.-B.; Huang, X.-C.; Lin, Y.-Y.; Chen, X.-M., Chem. Eur. J. 2005, 11, 552-561.
2004
58. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates Huang, X.-C.; Zhang, J.-P.; Chen, X.-M.J. Am. Chem. Soc. 2004, 126, 13218-13219.
59. (Cover Paper) Crystal-to-crystal transformations of a microporous metal-organic laminated framework triggered by guest exchange, dehydration and readsorption Zeng, M.-H.; Feng, X.-L.; Chen, X.-M.Dalton Trans. 2004, 2217-2223.(Highlighted in Chem. Sci.)
60. Syntheses, structures and photoluminescent properties of three silver(I) cluster-based coordination polymer with aromatic heterocycle carboxylates Yang, J.-H.; Zheng, S.-L.; Chen, X.-M.Cryst. Growth Des. 2004, 4, 831-836.
61. Syntheses, structures, and photoluminescence studies of [2:2] metallomacrocyclic silver(I) complexes with 1,3-bis(4,5-dihydro-1H-imidazol-2-yl)benzene Ren, C.-X.; Ye, B.-H.; He, F.; Cheng, L.;Chen, X.-M.CrystEngComm 2004, 6, 200-207.
62. A single-source approach to Bi2S3 and Sb2S3 nanorods via hydrothermal treatmentXie, G.; Qiao, Z.-P.; Zeng, M.-H.;Chen, X.-M.; Gao, S.-L., Cryst. Growth Des. 2004, 4, 513-516.
63. Two new mixed-valence Cu(I,II) imidazolate coordination polymers: Metal-valence tuning approach for new topologic structures Huang, X.-C.; Zhang, J.-P.; Lin, Y.-Y.; Chen, X.-M., Chem. Commun. 2004, 1100-1101.
64. Syntheses, structures, photoluminescence and theoretical studies of d10 metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate Zheng, S.-L.; Yang, J.-H.; Yu, X.-L.; Chen, X.-M., W.-T. Wong, Inorg. Chem.2004, 43, 830-838.
65. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M.Angew. Chem. Int. Ed.2004, 43, 206-209.
2003
66. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.Coord. Chem. Rev. 2003, 246, 185-202.
67. Syntheses, structures, photoluminescence and theoretical studies of a novel class of d10 metal complexes of 1H-[1,10]phenanthrolin-2-one Zheng, S.-L.; Zhang, J.-P.; Chen, X.-M.; Huang, Z.-L.; Lin, Z.-Y.; Wong, W.-T., Chem. Eur. J.2003, 9, 3888-3896.
68. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one) Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M.J. Am. Chem. Soc. 2003, 125, 6882-6883.
2002
69. Double-stranded helices and molecular zippers assembled from single-stranded coordination polymers directed by supramolecular interactions Chen, X.-M.; Liu, G.-F., Chem. Eur. J. 2002, 8, 4811-4817.
70. Pseudo-polyrotaxane and b-sheet layer-based three-dimensional coordination polymers constructed with silver(I) salts and flexible pyridyl-type ligands Tong, M.-L.; Wu, Y.-M.; Ru, J.; Chen, X.-M., H.-C. Chang, Kitagawa, S., Inorg. Chem. 2002, 41, 4846-4848.
71. Metal cation-supported supramolecular crown ethers featuring hydrogen-bonded tetrameric unit of 2-hydroxy pyridines Tong, M.-L.; Lin, Z.-J.; Li, W.; Zheng, S.-L.; Chen, X.-M.Cryst. Growth Des. 2002, 2, 443-448.
72. Microwave-assisted elemental-direct-reaction route to nanocrystalline copper chalcogenides CuSe and Cu2Te Zhang, Y.; Qiao, Z.-P.; Chen, X.-M., J. Mater. Chem. 2002, 12, 2747-2748.
73. Syntheses, crystal structures and physical properties of dinuclear copper(I) and tetranuclear mixed valence copper(I,II) complexes with hydroxylated bipyridyl-like ligands Zhang, X.-M.; Tong, M.-L.; Gong, M.-L.; Lee, H.K.; Luo, L.; Li, J.-H.; Tong, Y.-X.; Chen, X.-M.Chem. Eur. J. 2002, 8, 3187-3194.
74. Interlocking of molecular rhombi into 2D polyrotaxane network via p-p interactions. Crystal structure of [Cu2(bpa)2(phen)2(H2O)]2×H2O (bpa2– = biphenyl-4,4¢-dicarboxylate, phen = 1,10-phenanthroline)Liu, G.-F.; Ye, B.-H.; Ling, Y.-H.; Chen, X.-M., Chem. Commun. 2002, 1442-1443.
75. A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions Tao, J.; Zhang, Y.; Tong, M.-L.; Chen, X.-M., Yuen, T.; Lin, C.L.; Huang, X.-Y.; Li, J., Chem. Commun. 2002, 1342-1343.
76. Synthesis, crystal structures and properties of six cubane-like transition metal complexes of di-2-pyridyl ketone in gem-diol form Tong, M.-L.; Lee, H.K.; Tong, Y.-X.; Zheng, S.-L.; Shi, J.-X.; Chen, X.-M.Dalton Trans. 2002, 1727-1734.
77. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes Zhang, X.-M.; Tong, M.-L.; Chen, X.-M.Angew. Chem. Int. Ed. 2002, 41, 1029-1031.
78. One-pot monomer self-assembly route to thin coatings core/shell PbS/poly(methyl methacrylate) nanocomposites Qiao, Z.-P.; Xie, G.; Huang, J.-M.; Zhao, S.-Y.; Chen, X.-M., J. Mater. Chem. 2002, 12, 611–613.
79. Self-assembly of new three-dimensional molecular architectures constructed from silver(I)-hexamethylenetetramine layers with supramolecular interactions Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.;Ng, S.W., Dalton Trans. 2002, 360-364.
2001
80. Syntheses, structures and properties of three novel coordination polymers of silver(I) aromatic dicarboxylates with hexamethylenetetramine exhibiting unique metal-p interaction Zheng, S.-L.; Tong, M.-L.; Tan, S.-D.; Wang, Y.; Shi, J.-X.; Tong, Y.-X.; Lee, H.K.; Chen, X.-M.Organometallics 2001, 20, 5319-5325.
81. Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits Chen, H.-J.; Mao. Z.-W.; Gao, S.; Chen, X.-M. Chem. Commun.2001, 2320-2321.
82. A blue photoluminescent three-dimensional coordination polymer constructed with helical [Zn33-OH)(µ2-OH)]¥chains and mixed organic ligandsTao, J.; Tong, M.-L.; J.-X. Shi, Chen, X.-M., Inorg. Chem. 2001, 40, 6328-2330.
83. A novel supramolecular synthon for H-bonded coordination networks: syntheses and structures of extended 2-dimensional cadmium(II) arenedisulfonates Cai, J.-W.; Chen, C.-H.; Feng, X.-L.; Liao, C.-Z.; Chen, X.-M., Dalton Trans.2001, 2370–2375.
84. The unique dual role of zinc atoms in a mixed zinc-vanadium phosphate [Zn(phen)Zn(VO)(PO4)2] Zhang, X.-M.; Tong, M.-L.; Feng, S.-H.; Chen, X.-M.Dalton Trans. 2001, 2069-2070.
85. Syntheses and structures of three two-dimensional silver(I)-hexamethylenetetramine coordination polymers with new topologic motifs Zheng, S.-L.; Tong, M.-L.; Zhu, H.-l.; Fang, Y.; Chen, X.-M.Dalton Trans. 2001, 2049-2053.
86. Toward designed assembly of microporous coordination networks constructed from the silver(I)-hexamethylenetetramine layers Zheng, S.-L.; Tong, M.-L.; Fu, R.-W.; Chen, X.-M.S.W. Ng, Inorg. Chem. 2001, 40, 3562-3569.
87. Hydrogen bonds induced change of geometry and crystallized form of copper(II) complexes: syntheses and crystal structure of copper(II) complexes with Schiff-base ligands containing two imidazolyl groupsLong, L.-S.; Cai, J.-W.; Ren, Y.-P.; Tong, Y.-X.; Chen, X.-M.; Ji, L.-N.; Huang, R.-B.; Zheng, L.-S., Dalton Trans. 2001, 845-849.
88. A novel polycatenated double-layered hybrid organic-inorganic material constructed from [Zn2(tp)(4,4¢-bpy)]n2n+layers and V4O124– pillars Tao, J.; Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Dalton Trans.2001,770-771.
89. Syntheses and structures of six chain-, ladder- and grid-like coordination polymers constructed from m-hexamethylenetetramine and silver salts Zheng, S.-L.; Tong, M.-L.; Chen, X.-M.Dalton Trans. 2001, 586-592.
90. Syntheses and crystal structures of four metal-organic coordination networks constructed form cadmium(II) thiocyanate and nicotinic derivatives with hydrogen bonds Yang, G.; Zhu, H.-G.; Liang, B.-H.; Chen, X.-M., Dalton Trans. 2001, 580-585.
91. Syntheses and crystal structures of five two-dimensional networks constructed from staircase-like silver(I) thiocyanate chains and bridging polyamines Ren, C.-X.; Zhu, H.-L.; Yang G.; Chen, X.-M.Dalton Trans. 2001, 85-90.
2000
92. Influence of ligand backbones and counter ions on structures of helical silver(I) complexes with di-Schiff bases derived from phthalaldehydes and diamine Zhu, H.-L.; Tong, Y.-X.; Chen, X.-M., J. Chem. Soc.Dalton Trans. 2000, 4182-4186.
93. Hydrothermal synthesis and crystal structures of [M(tp)(4,4’-bipy)] (M = Co(II), Cd(II) and Zn(II)): Three-dimensional coordination frameworks constructed with mixed terephthalate (tp) and 4,4’ bipyridine (4,4’-bipy) ligands Tao, J.; Tong, M.-L.; Chen, X.-M.J. Chem. Soc., Dalton Trans. 2000, 3669-3674.
94. Blue photoluminescent zinc co-ordination polymers with supertetranuclear coresTao, J.; Tong M.-L.; Shi, J.-X.; Chen, X.-M., Ng, S.W., Chem. Commun. 2000, 2043-2044.
95. An octanuclear copper(II) complex self-assembled with divalent gem-diol form anion of di-2-pyridyl ketone (dpd-2H) and 2-hydroxylpyridine. Synthesis, crystal structure and properties of [Cu8(dpd-2H)4(m2-O2CMe)4{2-(OH)C5H4N}4](ClO4)4×4H2O Tong, M.-L.; Lee, H. K.; Tong, Y.-X.; Chen, X.-M.; Mak, T.C.W., Inorg. Chem. 2000, 39, 4666-4669.
96. Self-assembly of two- and three-dimensional coordination networks with hexamethylenetetramine and different small simple silver(I) salts Tong, M.-L.; Zheng, S.-L.; Chen, X.-M.Chem. Eur. J. 2000, 6, 3729-3638.
97. Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]×6H2O Zhang, X.-M.; Tong, M.-L.; Chen, X.-M.Chem. Commun.2000, 1817-1818.
98. Organic-inorganic hybrid materials assembled through weak intermolecular interactions. Synthesis, structures and non-linear optical properties of [4,4’-bipyH2][M(NCS)4] (M = Mn2+, Co2+ and Zn2+; 4,4’-bipy = 4,4’-bipyridine)  Chen, H.-J.; Zhang, L.-Z.; Cai, Z.-G.; Yang, G.; Chen, X.-M.J. Chem. Soc. Dalton Trans. 2000, 2463-2467.
99. Influence of the counter-ions and ligands on structures of silver(I) helicates with di-Schiff bases containing imidazole groups Yang, S.-P.; Chen, X.-M.; L.-N. Ji, J. Chem. Soc., Dalton Trans. 2000, 2337-2344.
100. Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4’-bpy)3(H2O)2(phba)2](NO3)2×4H2O (M = Cu2+ or Co2+ ; 4,4’-bpy = 4,4’-bipyridine; phba = 4-hydroxybenzoate) Tong, M.-L.; Chen, H.-J.; Chen, X.-M., Inorg. Chem. 2000, 39, 2235-2238.
101. Anionic and neutral metal-4,4’-bipyridine networks. Synthesis, structures and thermal properties of one- and three-dimensional coordination polymers constructed by metal salts and 4,4’-bipyridineTong, M.-L.; Chen, X.-M.,CrystEngCom 2000, 1.
1999
102. A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4’-bipyridine)2(H2O)4]2+ cations and rich solvate 4,4’-bipyridine molecules throughhydrogen- bonding and p-p interactions Tong, M.-L.; Lee, H. K.; Chen, X.-M.; Huang, R.-B.; Mak, T.C.W., J. Chem. Soc. Dalton Trans. 1999, 3657-3659.
103. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N.Angew. Chem. Int. Ed.1999, 38, 2237-2240.
104. Synthesis and structures of carboxylate-bridged polynuclear copper(II)-lanthanide(III) complexes [CuLn(pyridinioacetate)5(H2O)5](ClO4)5·2H2O and [Cu3Nd2(pyridinioacetate)10(NO3)2(H2O)8](ClO48·4H2O Yang, Y.-Y.; Wu, Y.-L.; Long, L.-S.; Chen, X.-M.J. Chem. Soc., Dalton Trans. 1999, 2005-2008.
105. Synthesis, crystal structures and properties of copper(II) complexes of Schiff base derivativescontaining imidazole and b-alanine groups Long, L.-S.; Yang, S.-P.; Tong, Y.-X.; Mao, Z.-W.; Chen,X.-M.; Ji, L.-N. J. Chem. Soc., Dalton Trans. 1999, 1999-2004.
106. Two- and three-dimensional non-interpenetrating open-networks self-assembled by m4 hexamethylene-tetramine (hmt). Syntheses and structures of [Ag2(m4-hmt)(SO4)(H2O)]×4H2O and [Ag2(m4-hmt)(m2-O2CMe)](MeCO2)×4.5H2O Tong, M.-L.; Zheng, S.-L.; Chen, X.-M.Chem. Commun. 1999, 561-562.
1998
107. Synthesis, structures and magnetic properties of carboxylate-bridged tetranuclear copper(II)-lanthanoid(III) complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10·2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8 Chen, X.-M.; Wu, Y.-L.; Yang, Y.-Y; Aubin, S.M.J.; Hendrickson, D.N. Inorg. Chem. 1998, 37, 6186-6191.
108. Helical silver(I)-2,4'-bipyridine chains organized into 2-D networks by metal-counterion or metal- metal bonding. Structures of [Ag(2,4'-bipyridine)]X (X- = NO3- or ClO4-) Tong, M.-L.; Chen, X.-M.; Ye, B.-H.;Ng, S.W., Inorg. Chem.1998, 37, 5278-5281.
109. Clathration of two-dimensional coordination polymers: Syntheses and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2(2,4'-bpy)2×H2O and [Cu(4,4'-bpy)2(H2O)2](ClO4)4×(4,4'-H2bpy) (M = CdII, ZnII, bpy = bipyridine)Tong, M.-L.; Ye, B.-H.; Cai, J.-W.; Chen, X.-M., Ng, S.W., Inorg. Chem. 1998, 37, 2645-2650.
110. A novel two-dimensional rectangular network. Synthesis and structure of {[Cu(4,4'-bpy)(pyz)(H2O)2](PF6)2}n (4,4'-bpy = 4,4'-bipyridine, pyz = pyrazine) Tong, M.-L.; Yu, X.-L.; Chen, X.-M.; Mak, T.C.W., J. Chem. Soc., Dalton Trans.1998, 5-6.
1994—1997
111. The first metal-encapsulating star polysulphoxide incorporating 2-amino-1,3,4-thiadiazoleYang, C.; Chen, X.-M.; Lu, X.-Q.; Zhou, Q.-H.; Yang, Y.-S., J. Chem. Soc.Chem. Commun. 1997, 2041-2042.
112. Model complexes for the carboxylate-histidine-metal triad systems in metalloenzymes. Synthesis, crystal structures and spectroscopic properties of [M(Him)2(O2CMe)2] (M = ZnII or CoII, Him = imidazole). Chen, X.-M.; Ye, B.-H.; Huang, X.-C.; Xu, Z.-T., J. Chem. Soc., Dalton Trans. 1996, 3465-3468.
113. Novel octadecanuclear copper(II)-lanthanoid(III) clusters. Synthesis and structures of [Cu12Ln6(m3-OH)24(O2CCH2CH2NC5H5)12(H2O)16(m12-ClO4)](ClO4)17·16H2O (LnIII = GdIII or SmIII) Chen, X.-M.; Wu, Y.-L.; Tong, Y.-X.; Huang, X.-Y., J. Chem. Soc.Dalton Trans. 1996, 2443-2448.
114. Synthesis, crystal structure and luminescence properties of a europium(III) complex with a new planar aromatic tridentate N3 ligand Yang, C.; Chen, X.-M.; Zhang, W.-H.; Chen, J.; Yang, Y.-S.; Gong, M.-L., J. Chem. Soc., Dalton Trans. 1996, 1767-1768.
115. Synthesis and structure of a novel carboxylate-bridged heterometallic copper(II)-gadolinium(III) complex Chen, X.-M.; Tong, M.-L.; Wu, Y.-L.; Luo, Y.-J., J. Chem. Soc., Dalton Trans. 1996, 2181-2182.
116. Synthesis, structure and magnetic properties of a singly carboxylato-bridged dinuclear Mn(II) complex Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T.C.W., J. Chem. Soc., Dalton Trans. 1995, 4001-4004.
117. Polynuclear CuII12-MIII6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion: [Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)  Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601.
118. A model complex for the carboxylate-histidine-zinc system in zinc enzymes. Crystal structure of [Zn(Him)2(MeCO2)2] (Him = imidazole) Chen, X.-M.; Xu, Z.-T.; Huang, X.-C., J. Chem. Soc.Dalton Trans. 1994, 2331-2332.
119. A dinuclear zinc complex of biological relevance. Crystal structure of [Zn2(bpy)2(MeCO2)3]ClO4 Chen, X.-M.; Tong, Y.-X.; Mak, T.C.W., Inorg. Chem. 1994, 33, 4586-4588.

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